ethyldimethylamine alumane

• ChemBase ID: 148668
• Molecular Formular: C4H14AlN
• Molecular Mass: 103.142198
• Monoisotopic Mass: 103.09416308
• SMILES: CCN(C)C.[AlH3]
• Canonical SMILES: CCN(C)C.[AlH3]
• InChI: InChI=1S/C4H11N.Al/c1-4-5(2)3;/h4H2,1-3H3
• InChIKey: JFULSLYTSZPADJ-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: ethyldimethylamine alumane
• IUPAC Traditional name: ethyl dimethylamine alumane
• Synonyms: (Ethyldimethylamine)trihydroaluminum; Dimethylethylamine alane; Alane N,N-dimethylethylamine complex solution; N,N-二甲基乙胺醛烷络合物 溶液

Database IDs

• CAS Number: 124330-23-0
• MDL Number: MFCD00191709
• PubChem SID: 162242843; 24864913
• PubChem CID: 11115999

CALCULATED PROPERTIES

• H Acceptors: 1
• H Donor: 0
• LogD (pH = 5.5): -2.8838933
• LogD (pH = 7.4): -1.779944
• Log P: 0.5469774
• Molar Refractivity: 24.7367 cm^3
• Polarizability: 9.648022 Å^3
• Polar Surface Area: 3.24 Å^2
• Rotatable Bonds: 1
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Flash Point: -20 °C; -4 °F
• Density: 0.837 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Flammable (F); Harmful (Xn)
• UN Number: 3399
• German water hazard class: 3
• Hazard Class: 4.3
• Packing Group: 2
• Risk Statements: 63-11-14/15-36/38-48/20-65-67
• Safety Statements: 16-26-36/37-43-62
• GHS Pictograms: GHS02; GHS05; GHS07; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H250-H261-H304-H314-H336-H361d-H373
• GHS Precautionary statements: P210-P222-P231 + P232-P261-P280-P422
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 3399 4.3/PG 2
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Concentration: 0.5 M in toluene
• Linear Formula: C2H5N(CH3)2 · AlH3

DETAILS

Sigma Aldrich - 400386

Packaging
50, 100 mL in Sure/Seal™
Application
Reactant for:
• Preparation of aluminum nanoparticles1
• Fluorination reactions2
• Aluminum metal-organic chemical vapor deposition for the growth of aluminum films3
• Ligand-exchange reactions4
• Hydroalumination of nitriles and isonitriles5