fluorosilver

• ChemBase ID: 148112
• Molecular Formular: AgF
• Molecular Mass: 126.8666032
• Monoisotopic Mass: 125.90350022
• SMILES: F[Ag]
• Canonical SMILES: F[Ag]
• InChI: InChI=1S/Ag.FH/h;1H/q+1;/p-1
• InChIKey: REYHXKZHIMGNSE-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: fluorosilver
• IUPAC Traditional name: silver monofluoride
• Synonyms: Silver(I) fluoride; 氟化银(I)

Database IDs

• CAS Number: 7775-41-9
• EC Number: 231-895-8
• MDL Number: MFCD00003410
• PubChem SID: 24853595; 24853594; 162242289
• PubChem CID: 62656

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.2225
• LogD (pH = 7.4): 0.2225
• Log P: 0.2225
• Molar Refractivity: 1.5013 cm^3
• Polarizability: 5.4984436 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: powder
• Melting Point: ≥300 °C(lit.)
• Boiling Point: 1159 °C/1 atm(lit.)
• Density: 5.852 g/mL at 25 °C(lit.)

Safety Information

• RTECS: VW4250000
• European Hazard Symbols: Corrosive (C)
• UN Number: 3260
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 23/24/25-34
• Safety Statements: 26-28-36/37/39-45
• GHS Pictograms: GHS05; GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H301 + H311 + H331-H315-H318
• GHS Precautionary statements: P261-P280-P301 + P310-P305 + P351 + P338-P311
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3260 8/PG 2

Product Information

• Purity: ≥99.0%; ≥99.0% (AT); ≥99.9% trace metals basis; 99%
• Grade: puriss. p.a.
• Cation Traces: Ca: ≤10 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤10 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Na: ≤200 mg/kg; Ni: ≤10 mg/kg; Pb: ≤50 mg/kg; Zn: ≤10 mg/kg
• Antion Traces: chloride (Cl-): ≤50 mg/kg; sulfate (SO42-): ≤50 mg/kg
• Empirical Formula (Hill Notation): AgF

DETAILS

Sigma Aldrich - 226866

Packaging
5, 25 g in amber poly

Sigma Aldrich - 226858

Application
Preparation of bromoacetylenes from bulky, trialkylsilylacetylenes.1 Also used in a palladium-catalyzed cross coupling of acetanilides with trialkoxysilanes.2
Packaging
1, 5, 25 g in amber poly