dichloroplatinum; bis(triphenylphosphane)

• ChemBase ID: 148078
• Molecular Formular: C36H30Cl2P2Pt
• Molecular Mass: 790.554922
• Monoisotopic Mass: 789.08477058
• SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Cl[Pt]Cl
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Cl[Pt]Cl
• InChI: InChI=1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChIKey: XAFJSPPHVXDRIE-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: dichloroplatinum; bis(triphenylphosphane)
• IUPAC Traditional name: platinum(II) chloride; bis(triphenylphosphine)
• Synonyms: Pt(PPh3)2Cl2; cis-Bis(triphenylphosphine)platinum(II) dichloride; cis-Dichlorobis(triphenylphosphine)platinum(II); trans-Bis(triphenylphosphine)platinum dichloride; trans-Dichlorobis(triphenylphosphine)platinum(II); 顺-二(三苯基膦)二氯化铂(II); 顺-二氯双(三苯基膦)铂(II); 反-二氯双(三苯基膦)铂(II)

Database IDs

• CAS Number: 14056-88-3; 15604-36-1
• MDL Number: MFCD00010825
• PubChem SID: 162242255; 24857337; 24854719
• PubChem CID: 6102097

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• Molar Refractivity: 81.6229 cm^3
• Polarizability: 32.34495 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 6
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Melting Point: ≥300 °C(lit.)

Safety Information

• European Hazard Symbols: Irritant (Xi)
• German water hazard class: 3
• Risk Statements: 36/37/38
• Safety Statements: 26; 26-37/39
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves

Product Information

• Linear Formula: [(C6H5)3P]2PtCl2

DETAILS

Sigma Aldrich - 288403

Packaging
1 g in glass bottle
Application
Catalyst for:
• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups1
• Alkynylation and hydrogenation reactions2
• Hetero-Diels-Alder/ring-opening reactions3
• Insertion of carbenes into O-H bonds of alcohols4
• Cyclopropanation of olefins5
• Hydroformylation reactions6

Sigma Aldrich - 244945

Packaging
1 g in glass bottle