tetrakis(triphenylphosphane) platinum

• ChemBase ID: 148075
• Molecular Formular: C72H60P4Pt
• Molecular Mass: 1244.219844
• Monoisotopic Mass: 1243.32933944
• SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Pt]
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Pt]
• InChI: InChI=1S/4C18H15P.Pt/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H
• InChIKey: SYKXNRFLNZUGAJ-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: tetrakis(triphenylphosphane) platinum
• IUPAC Traditional name: tetrakis(triphenylphosphine) platinum
• Synonyms: Pt(PPh3)4; Platinum(0)-tetrakis(triphenylphosphine); Tetrakis(triphenylphosphine)platinum(0); Platinum(0) tetrakis(triphenylphosphine); 四(三苯基膦)铂(0); 四(三苯基膦)铂; 四(三苯基膦)铂)

Database IDs

• CAS Number: 14221-02-4
• EC Number: 238-087-4
• MDL Number: MFCD00010014
• PubChem SID: 24854721; 162242252
• PubChem CID: 11979705

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• Molar Refractivity: 81.6229 cm^3
• Polarizability: 32.34495 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 12
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Solubility: Soluble in benzene
• Apperance: Crystalline Powder

Safety Information

• Storage Warning: Air Sensitive
• European Hazard Symbols: X
• German water hazard class: 3
• Risk Statements: 22
• Safety Statements: 36
• TSCA Listed: 是
• GHS Pictograms: GHS06
• GHS Hazard statements: H301
• GHS Precautionary statements: P264-P270-P301+P310-P321-P405-P501A
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C

Product Information

• Purity: 97%; Pt 15.2% min
• Linear Formula: Pt[(C6H5)3P]4

DETAILS

Sigma Aldrich - 244961

Application
Used as a precursor to platinum complexes.
Packaging
1, 5 g in glass bottle

REFERENCES

• Catalyst for the diboronylation of alkynes with Bis(pinacolato)diboron, L16088, to give cis-bis-boryl alkenes: Organometallics, 15, 713 (1996), and of 1,3-dienes to give 1,4-bis-boryl-2-alkenes: Chem. Commun., 2073 (1996):
  
• Similarly, allenes are converted to 2,3-bis-borylalkenes: Tetrahedron Lett., 39, 2357 (1998).