trichlororuthenium hydrate

• ChemBase ID: 146985
• Molecular Formular: Cl3H2ORu
• Molecular Mass: 225.44428
• Monoisotopic Mass: 224.82147172
• SMILES: O.Cl[Ru](Cl)Cl
• Canonical SMILES: Cl[Ru](Cl)Cl.O
• InChI: InChI=1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
• InChIKey: BIXNGBXQRRXPLM-UHFFFAOYSA-K

NAMES AND DATABASE IDS

Names

• IUPAC name: trichlororuthenium hydrate
• IUPAC Traditional name: trichlororuthenium hydrate
• Synonyms: Ruthenium(III) chloride hydrate; 三氯化钌 水合物

Database IDs

• CAS Number: 14898-67-0
• EC Number: 233-167-5
• MDL Number: MFCD00149844
• PubChem SID: 24870096; 24888172; 24852386; 162241177
• PubChem CID: 6093376

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.9035
• LogD (pH = 7.4): 1.9035
• Log P: 1.9035
• Molar Refractivity: 18.4089 cm^3
• Polarizability: 11.720871 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: powder and chunks

Safety Information

• European Hazard Symbols: Corrosive (C)
• UN Number: 3260
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• GHS Pictograms: GHS05
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3260 8/PG 2

Product Information

• Purity: 38.0-42.0% Ru basis; 99.98% trace metals basis
• Grade: ReagentPlus®
• Compostion: Degree of hydration, ≤1; Ruthenium content, 40.00-49.00%
• Linear Formula: RuCl3 · xH2O

DETAILS

Sigma Aldrich - 84050

Other Notes
Catalyst for oxidation reactions with an oxidant1,2; review3
Packaging
1, 5 g in glass bottle

Sigma Aldrich - 463779

Application
Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
Used for the selective hydrogenation of unsaturated aldehydes.
Used with aluminum tri-sec-butoxide (201073) to prepare a nanoparticulate catalyst for acceptor-free dehydrogenation of alcohols to aldehydes and ketones.
Other Notes
soluble form
Packaging
1, 5 g in glass bottle

Sigma Aldrich - 206229

Application
Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
Used recently to prepare a nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation arylmethyl alcohols to the corresponding aldehydes.
General description
soluble form
Packaging
1, 5, 25 g in glass bottle
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC