pentachlorostibane

• ChemBase ID: 146958
• Molecular Formular: Cl5Sb
• Molecular Mass: 299.025
• Monoisotopic Mass: 295.7480784
• SMILES: Cl[Sb](Cl)(Cl)(Cl)Cl
• Canonical SMILES: Cl[Sb](Cl)(Cl)(Cl)Cl
• InChI: InChI=1S/5ClH.Sb/h5*1H;/q;;;;;+5/p-5
• InChIKey: VMPVEPPRYRXYNP-UHFFFAOYSA-I

NAMES AND DATABASE IDS

Names

• IUPAC name: pentachlorostibane
• IUPAC Traditional name: antimony pentachloride
• Synonyms: Antimony(V) chloride solution; Antimony pentachloride; Antimony(V) chloride; Antimony(V) chloride, ultra dry; 氯化锑(V) 溶液; 五氯化锑; 氯化锑(V); 氯化锑(III), 超干

Database IDs

• CAS Number: 7647-18-9
• EC Number: 231-601-8
• MDL Number: MFCD00011213
• Merck Index: 14695
• PubChem SID: 24855017; 24852875; 24868645; 24860583; 162241150
• PubChem CID: 24294

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.1781
• LogD (pH = 7.4): 3.1781
• Log P: 3.1781
• Molar Refractivity: 30.6815 cm^3
• Polarizability: 16.982832 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: Soluble in HCl, chloroform, carbon tetrachloride
• Apperance: liquid; Liquid; Liquid, Ampouled under argon
• Melting Point: 2.8 °C(lit.); 2.8°C
• Boiling Point: 79°C/22mm; 92 °C/30 mmHg(lit.)
• Density: 1.442 g/mL at 25 °C; 2.336; 2.36 g/mL at 25 °C(lit.)
• Refractive Index: 1.601
• Vapor Pressure: 0.13 psi ( 55 °C)
• Vapor Density: >10.2 (vs air)

Safety Information

• Storage Warning: Moisture Sensitive
• RTECS: CC5075000
• European Hazard Symbols: Corrosive (C); Nature polluting (N); Toxic (T)
• UN Number: 1730; 3289; UN1730
• German water hazard class: 2
• Hazard Class: 6.1; 8
• Packing Group: 2; II
• Risk Statements: 14-23/24/25-34-40; 34-51/53
• Safety Statements: 23-26-36/37/39-45; 26-45-61
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS09
• GHS Signal Word: Danger
• GHS Hazard statements: H314-H411
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A; P273-P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1730 8/PG 2; UN 3289 6.1/PG 2

Product Information

• Purity: ≥99.99% trace metals basis; ≥99.999% trace metals basis; 99%; 99.999% (metals basis)
• Concentration: 1.0 M in methylene chloride
• Grade: anhydrous
• Linear Formula: SbCl5

DETAILS

Sigma Aldrich - 338877

Packaging
5, 25 g in glass bottle

Sigma Aldrich - 215171

Packaging
1 kg in glass bottle
50, 250 g in glass bottle

Sigma Aldrich - 451673

Packaging
1, 10 g in ampule

Sigma Aldrich - 249858

Packaging
100 mL in Sure/Seal™

Sigma Aldrich - 01-6070

Suitability
PCB analysis

REFERENCES

• For a review of antimony pentachloride as a Friedel-Crafts catalyst, see: Synthesis, 345 (1980). Used catalytically in moist acetonitrile to provide a mild, selecitve system for the deprotection of tert-butyldimethysilyl derivatives of amines, phenols, primary alcohols and aryl carboxylic acids: Tetrahedron Lett., 44, 8819 (2003). For a brief feature on uses in synthesis, see: Synlett, 1486 (2005).