pentafluoro-λ5-phosphane hydrofluoride

• ChemBase ID: 146503
• Molecular Formular: F6HP
• Molecular Mass: 145.9721202
• Monoisotopic Mass: 145.97200598
• SMILES: F.FP(F)(F)(F)F
• Canonical SMILES: FP(F)(F)(F)F.F
• InChI: InChI=1S/F5P.FH/c1-6(2,3,4)5;/h;1H
• InChIKey: OQWOLAMXNGPSQY-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: pentafluoro-λ^5-phosphane hydrofluoride
• IUPAC Traditional name: phosphorus pentafluoride hydrofluoride
• Synonyms: Hydrogen hexafluorophosphate; Hexafluorophosphoric acid solution; 六氟合磷氢酸; 六氟磷酸 溶液

Database IDs

• CAS Number: 16940-81-1
• MDL Number: MFCD00011350
• PubChem SID: 162240698; 24851984
• PubChem CID: 11073554

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.0125
• LogD (pH = 7.4): 2.0125
• Log P: 2.0125
• Molar Refractivity: 12.7065 cm^3
• Polarizability: 4.5844684 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Density: 1.651 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Corrosive (C); Highly toxic (T+)
• UN Number: 1782
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 14-26/27/28-35; 26/27/28-35
• Safety Statements: 26-28-36/37/39-45
• GHS Pictograms: GHS05; GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H300-H310-H314-H331
• GHS Precautionary statements: P261-P264-P280-P301 + P310-P302 + P350-P305 + P351 + P338
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1782 8/PG 2
• Supplemental Hazard Statements: Reacts violently with water.
• Storage Temperature: 2-8°C

Product Information

• Purity: 60% solution based on PF6- only basis; 70% solution based on hydrolysis products and PF6- basis
• Concentration: ~65 wt. % in H2O; ~65% in H2O (gravimetric)
• Grade: technical
• Impurities: ~10% hydrofluoric acid
• Linear Formula: HPF6

DETAILS

Sigma Aldrich - 200956

Packaging
25, 500 g in poly bottle