λ1-indiganyliumylidene iodide

• ChemBase ID: 145283
• Molecular Formular: IIn
• Molecular Mass: 241.72247
• Monoisotopic Mass: 241.808351
• SMILES: [In+].[I-]
• Canonical SMILES: [In+].[I-]
• InChI: InChI=1S/HI.In/h1H;/q;+1/p-1
• InChIKey: FOVZCYAIUZHXGB-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: λ^1-indiganyliumylidene iodide
• IUPAC Traditional name: λ^1-indiganyliumylidene iodide
• Synonyms: Indium(I) iodide; Indium(I) iodide, ultra dry; 碘化亚铟; 碘化亚铟(I), 超干

Database IDs

• CAS Number: 13966-94-4
• EC Number: 237-746-3
• MDL Number: MFCD00135543
• PubChem SID: 162239491; 24880940; 24865876
• PubChem CID: 71311153

CALCULATED PROPERTIES

• Acid pKa: 1.11
• H Acceptors: 0
• H Donor: 0
• Log P: 0.0
• Molar Refractivity: 0.0 cm^3
• Polarizability: 5.2620425 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true
• LogD (pH = 5.5): 0.0
• LogD (pH = 7.4): 0.0

PROPERTIES

Physical Property

• Apperance: -10 Mesh Beads, Ampouled under argon; beads; powder
• Melting Point: 351°C

Safety Information

• Storage Warning: Moisture Sensitive
• European Hazard Symbols: Corrosive (C); Harmful (Xn)
• UN Number: UN3260
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: III
• Risk Statements: 22-36/37/38-42/43; 34
• Safety Statements: 22-26-36/37-45; 26-36/37/39-45
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS07; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H302-H315-H319-H334-H335; H314-H318
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A; P261-P305 + P351 + P338-P342 + P311
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Product Information

• Purity: 99.998% (metals basis); 99.999% trace metals basis
• Grade: anhydrous
• Particle Size: -10 mesh
• Linear Formula: InI

DETAILS

Sigma Aldrich - 578606

Packaging
2, 10 g in ampule

Sigma Aldrich - 413658

Application
Has been discovered and used as a reagent to propagate some organic reactions, such as cyclization1,2 and cleavage of diselenide or disulfide.3,4 Can also be used to prepare In-containing complexes.5
Packaging
1, 5 g in ampule