bis([bis(dimethylamino)alumanyl]dimethylamine)

• ChemBase ID: 144985
• Molecular Formular: C12H36Al2N6
• Molecular Mass: 318.417516
• Monoisotopic Mass: 318.26322244
• SMILES: CN(C)[Al](N(C)C)N(C)C.CN(C)[Al](N(C)C)N(C)C
• Canonical SMILES: CN([Al](N(C)C)N(C)C)C.CN([Al](N(C)C)N(C)C)C
• InChI: InChI=1S/6C2H6N.2Al/c6*1-3-2;;/h6*1-2H3;;/q6*-1;2*+3
• InChIKey: JGZUJELGSMSOID-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: bis([bis(dimethylamino)alumanyl]dimethylamine)
• IUPAC Traditional name: bis([bis(dimethylamino)alumanyl]dimethylamine)
• Synonyms: Tris(dimethylamido)aluminum(III); Aluminum dimethylamide; Hexakisdimethylamide dialuminum; Tris(dimethylamino)aluminum dimer; 三(二甲基酰胺基)铝(III); 三(二甲胺基)铝二聚体

Database IDs

• CAS Number: 32093-39-3
• MDL Number: MFCD00269811
• PubChem SID: 24870625; 162239196
• PubChem CID: 16688802

CALCULATED PROPERTIES

• H Acceptors: 3
• H Donor: 0
• LogD (pH = 5.5): -1.9357058
• LogD (pH = 7.4): -0.5402636
• Log P: -0.3854
• Molar Refractivity: 41.6802 cm^3
• Polarizability: 18.869843 Å^3
• Polar Surface Area: 9.72 Å^2
• Rotatable Bonds: 6
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: Powder, packaged under argon; solid
• Melting Point: 82-84 °C(lit.); 87-89°C
• Boiling Point: 90°C/0.05mm subl.
• Flash Point: 21 °C; 21°C(70°F); 69.8 °F
• Density: 0.865; 0.865 g/mL at 25 °C(lit.)

Safety Information

• Storage Warning: Moisture Sensitive
• European Hazard Symbols: Corrosive (C); Flammable (F)
• UN Number: 3131; UN3131
• German water hazard class: 3
• Hazard Class: 4.3
• Packing Group: 1; I
• Risk Statements: 11-14/15-34
• Safety Statements: 16-26-36/37/39-43; 7/8-16-26-36/37/39-45
• TSCA Listed: 否
• GHS Pictograms: GHS02; GHS05
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H260-H314-H318; H260-H314
• GHS Precautionary statements: P210-P280-P303+P361+P353-P305+P351+P338-P310-P402+P404; P223-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3131 4.3/PG 1
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Linear Formula: Al(N(CH3)2)3

DETAILS

Sigma Aldrich - 469947

General description
Atomic number of base material: 13 Aluminum
Packaging
10 g in glass bottle
Application
Precursor to aluminum nitride (AlN) thin films by organometallic chemical vapor deposition (OMCVD).1