bis(chlororhodium); tetrakis(ethene)

• ChemBase ID: 142551
• Molecular Formular: C8H16Cl2Rh2
• Molecular Mass: 388.92964
• Monoisotopic Mass: 387.87391387
• SMILES: C=C.C=C.C=C.C=C.Cl[Rh].Cl[Rh]
• Canonical SMILES: C=C.C=C.C=C.C=C.[Rh]Cl.[Rh]Cl
• InChI: InChI=1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2
• InChIKey: OOQJCPOXJFCGCR-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: bis(chlororhodium); tetrakis(ethene)
• IUPAC Traditional name: bis(chlororhodium); tetrakis(ethylene)
• Synonyms: Bis[chlorobis(ethylene)rhodium]; Bis[chlorodiethylenerhodium]; Chlorobis(ethylene)rhodium dimer; Dichlorotetra(ethene)dirhodium; Dichlorotetrakis(ethene)dirhodium; Diethylenerhodium chloride dimer; Divinylrhodium chloride dimer; Tetrakis(ethylene)dichlorodirhodium; [Rh(C2H4)2Cl]2; Di-μ-chlorotetraethylene dirhodium(I); 二(乙烯)氯铑二聚体

Database IDs

• CAS Number: 12081-16-2
• EC Number: 235-145-0
• MDL Number: MFCD00013206
• PubChem SID: 24884230

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.1068089
• LogD (pH = 7.4): 1.1068089
• Log P: 1.1068089
• Molar Refractivity: 9.9758 cm^3
• Polarizability: 4.227136 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Safety Information

• German water hazard class: 3
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: -20°C

Product Information

• Empirical Formula (Hill Notation): C8H16Cl2Rh2

DETAILS

Sigma Aldrich - 656763

Application
Precursor to Rh(I) norbornadiene catalyst used in an asymmetric 1,4-addition of arylboronic acids to cyclic enones.1
Packaging
1 g in glass bottle
100 mg in glass bottle