bis(chlorolithium); trichlorolanthanum

• ChemBase ID: 141064
• Molecular Formular: Cl5LaLi2
• Molecular Mass: 330.0525
• Monoisotopic Mass: 327.7826255
• SMILES: [Li]Cl.[Li]Cl.Cl[La](Cl)Cl
• Canonical SMILES: Cl[La](Cl)Cl.Cl[Li].Cl[Li]
• InChI: InChI=1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
• InChIKey: YSKOYVQYUJUXCN-UHFFFAOYSA-I

NAMES AND DATABASE IDS

Names

• IUPAC name: bis(chlorolithium); trichlorolanthanum
• IUPAC Traditional name: lanthanum(III) chloride; bis(lithium chloride)
• Synonyms: Lanthanum trichloride lithium chloride complex; Lanthanum(III) chloride bis(lithium chloride) complex solution; 三氯化镧氯化锂络合物; 氯化镧(III)双(氯化锂)络合物 溶液

Database IDs

• CAS Number: 405204-22-0
• PubChem SID: 162235299
• PubChem CID: 71310563

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.9035
• LogD (pH = 7.4): 1.9035
• Log P: 1.9035
• Molar Refractivity: 18.4089 cm^3
• Polarizability: 12.848276 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Flash Point: 17 °C; 62.6 °F
• Density: 1.05 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Flammable (F); Irritant (Xi)
• UN Number: 2056
• German water hazard class: 3
• Hazard Class: 3
• Packing Group: 2
• Risk Statements: 11-19-36/37/38
• Safety Statements: 16-26
• GHS Pictograms: GHS02; GHS07; GHS09
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H315-H319-H335-H400
• GHS Precautionary statements: P210-P261-P273-P305 + P351 + P338
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2056 3/PG 2
• Supplemental Hazard Statements: May form explosive peroxides.

Product Information

• Concentration: 0.6 M in THF; 16 % (w/w)
• Linear Formula: LaCl3 · 2LiCl

DETAILS

Sigma Aldrich - 703559

Packaging
100 mL in Sure/Seal™
Legal Information
Product of Rockwood Lithium
Application
Selective 1,2-Additions with LaCl3
•2LiCl
• Mediates Grignard additions1
• Reagent for metal exchange reactions2
• Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines3