bis(tri-tert-butylphosphane) platinum

• ChemBase ID: 140816
• Molecular Formular: C24H54P2Pt
• Molecular Mass: 599.711082
• Monoisotopic Mass: 599.33486599
• SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pt]
• Canonical SMILES: CC(P(C(C)(C)C)C(C)(C)C)(C)C.CC(P(C(C)(C)C)C(C)(C)C)(C)C.[Pt]
• InChI: InChI=1S/2C12H27P.Pt/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3
• InChIKey: RJQWVEJVXWLMRE-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: bis(tri-tert-butylphosphane) platinum
• IUPAC Traditional name: bis(tri-tert-butylphosphane) platinum
• Synonyms: Bis[tris(1,1-dimethylethyl)phosphine]platinum; Bis(tri-tert-butylphosphine)platinum(0); 双(三叔丁基膦)铂(0)

Database IDs

• CAS Number: 60648-70-6
• MDL Number: MFCD04974248
• PubChem SID: 162235056
• PubChem CID: 6097049

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.3845654
• LogD (pH = 7.4): 2.3847759
• Log P: 2.5937
• Molar Refractivity: 68.517 cm^3
• Polarizability: 25.590317 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 6
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Melting Point: 260-269 °C

Safety Information

• German water hazard class: 3
• Storage Temperature: 2-8°C

Product Information

• Linear Formula: [((CH3)3C)3P]2Pt

DETAILS

Sigma Aldrich - 682691

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Reactant for synthesis of:
• Trimetallic ReBiPt complexes1
• Rhodium-germanium carbonyl complexes2Catalyst for the synthesis of:
• Amidobipyridyl inhibitors of protein kinase D3
• 5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling4Catalyst for phenyl and methyl group transfer from tin to iridium5Activator of metal hydride complexes6