alumanoylol palladium

• ChemBase ID: 140303
• Molecular Formular: AlH2O2Pd
• Molecular Mass: 167.416218
• Monoisotopic Mass: 166.89050393
• SMILES: O[AlH]=O.[Pd]
• Canonical SMILES: O[AlH]=O.[Pd]
• InChI: InChI=1S/Al.H2O.O.Pd/h;1H2;;/q+1;;;/p-1
• InChIKey: BBEPUHUDSUQPRM-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: alumanoylol palladium
• IUPAC Traditional name: AlO(OH) palladium
• Synonyms: Palladium nanoparticles entrapped in aluminum hydroxide matrix; 包封于氢氧化铝基体内的钯纳米粒子

Database IDs

• PubChem SID: 162234547; 24885199
• PubChem CID: 16218279

CALCULATED PROPERTIES

• Acid pKa: 3.0
• H Acceptors: 2
• H Donor: 1
• LogD (pH = 5.5): -1.5039775
• LogD (pH = 7.4): -1.698255
• Log P: 0.5624
• Molar Refractivity: 4.0075 cm^3
• Polarizability: 3.7933986 Å^3
• Polar Surface Area: 37.3 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Product Information

• Linear Formula: Pd/AlO(OH)

DETAILS

Sigma Aldrich - 674133

Application
A recyclable nanocatalyst for the racemization of primary amines. When used in conjunction with a lipase produces enantiopure amines by Dynamic Kinetic Resolution.3
Catalyst for:
• Solvent-free hydrogenation1
• Aerobic alcohol oxidation2
General description
A robust palladium heterogenous catalyst.2
Packaging
10 g in glass bottle