lithiumamine

• ChemBase ID: 140085
• Molecular Formular: H2LiN
• Molecular Mass: 22.96358
• Monoisotopic Mass: 23.03472862
• SMILES: [Li]N
• Canonical SMILES: [Li]N
• InChI: InChI=1S/Li.H2N/h;1H2/q+1;-1
• InChIKey: AFRJJFRNGGLMDW-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: lithiumamine
• IUPAC Traditional name: lithiumamine
• Synonyms: Lithium amide; 氨基化锂

Database IDs

• CAS Number: 7782-89-0
• EC Number: 231-968-4
• MDL Number: MFCD00011093
• PubChem SID: 162234329; 24852671
• PubChem CID: 24532

CALCULATED PROPERTIES

• Molar Refractivity: 5.2841 cm^3
• Polarizability: 3.4645104 Å^3
• Polar Surface Area: 26.02 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true
• H Acceptors: 1
• H Donor: 1
• LogD (pH = 5.5): -0.6334086
• LogD (pH = 7.4): -0.34407595
• Log P: -0.3388

PROPERTIES

Physical Property

• Apperance: powder
• Melting Point: 380-400 °C
• Density: 1.178 g/mL at 25 °C(lit.)

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F)
• UN Number: 1390
• German water hazard class: 2
• Hazard Class: 4.3
• Packing Group: 2
• Risk Statements: 14/15-29-34
• Safety Statements: 26-36/37/39-43-45
• GHS Pictograms: GHS02; GHS05
• GHS Signal Word: Danger
• GHS Hazard statements: H261-H314
• GHS Precautionary statements: P231 + P232-P280-P305 + P351 + P338-P310-P422
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1390 4.3/PG 2
• Supplemental Hazard Statements: Contact with water liberates toxic gas., Reacts violently with water.

Product Information

• Purity: 95%
• Grade: hydrogen-storage grade
• Linear Formula: LiNH2

DETAILS

Sigma Aldrich - 213217

Packaging
5, 100, 500 g in glass bottle
Application
Reagent for synthesis of: Antiinflamatory and preoresolving protectin D11 Chemotype dipeptidyl peptidase IV inhibitors2 Sterically congested triarylamines3 Dyes displaying large Stokes shifts4 GM1 ganglioside derivatives5Reagent for cross-coupling of aryl chlorides and amines6

Sigma Aldrich - 686050

Analysis Note
Hydrogen content, XRD plots and metal purity data are available upon request.
Packaging
10 g in glass bottle
Protocols & Applications
Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors