mercury(2+) ion hydrate dinitrate

• ChemBase ID: 138905
• Molecular Formular: H2HgN2O7
• Molecular Mass: 342.61508
• Monoisotopic Mass: 343.95684341
• SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.[Hg+2]
• Canonical SMILES: [O-][N+](=O)[O-].[O-][N+](=O)[O-].O.[Hg+2]
• InChI: InChI=1S/Hg.2NO3.H2O/c;2*2-1(3)4;/h;;;1H2/q+2;2*-1
• InChIKey: KVICROHOONHSRH-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: mercury(2+) ion hydrate dinitrate
• IUPAC Traditional name: mercury(2+) ion hydrate dinitrate
• Synonyms: Mercuric nitrate monohydrate; Mercury(II) nitrate monohydrate; Mercury(II) nitrate hydrate, ACS; 硝酸汞 一水合物; 硝酸汞(II) 一水合物; 硝酸汞(II)水合物, ACS

Database IDs

• CAS Number: 7783-34-8
• EC Number: 233-886-4; 233-152-3
• MDL Number: MFCD00149736
• Merck Index: 145880
• PubChem SID: 24873909; 162233156; 24887943; 24853804
• PubChem CID: 3084029

CALCULATED PROPERTIES

• Acid pKa: -1.3999903
• H Acceptors: 3
• H Donor: 0
• LogD (pH = 5.5): 0.8368004
• LogD (pH = 7.4): 0.8368004
• Log P: 0.8368004
• Molar Refractivity: 8.3471 cm^3
• Polarizability: 3.4222581 Å^3
• Polar Surface Area: 66.2 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: Crystalline
• Melting Point: 79 °C(lit.); 79°C
• Density: 4.39

Safety Information

• Storage Warning: Hygroscopic
• RTECS: OW8225000
• European Hazard Symbols: Nature polluting (N); Oxidising (O); Highly toxic (T+)
• UN Number: 1625; UN1625
• German water hazard class: 3
• Hazard Class: 6.1
• Packing Group: 2; II
• Risk Statements: 26/27/28-33-50/53; 8-26/27/28-33-50/53
• Safety Statements: 13-28-45-60-61
• TSCA Listed: 是
• GHS Pictograms: GHS03; GHS06; GHS08; GHS09
• GHS Signal Word: Danger
• GHS Hazard statements: H300-H310-H330-H272-H373-H400-H410; H300-H310-H330-H373-H410
• GHS Precautionary statements: P221-P301+P310-P304+P340-P320-P330-P361-P405-P501A; P260-P264-P273-P280-P284-P301 + P310
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1625 6.1/PG 2

Product Information

• Purity: ≥97.0% (precipitation titration); ≥98.0%; ≥98.5% (T); ≥99.99% trace metals basis; 98.0% min
• Grade: ACS reagent; puriss. p.a.; purum p.a.
• Ignition Residue: ≤0.01% (after reduction)
• Impurities: <100 ppm total metallic impurities
• Cation Traces: Ca: ≤10 mg/kg; Ca: ≤50 mg/kg; Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: ≤0.001%; Fe: ≤10 mg/kg; Fe: ≤50 mg/kg; Hg+: ≤0.2%; Hg+: ≤2000 mg/kg; K: ≤100 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Na: ≤100 mg/kg; Na: ≤50 mg/kg; Ni: ≤5 mg/kg; Ni: ≤50 mg/kg; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: chloride (Cl-): ≤0.002%; chloride (Cl-): ≤20 mg/kg; chloride (Cl-): ≤50 mg/kg; sulfate (SO42-): ≤0.002%; sulfate (SO42-): ≤20 mg/kg; sulfate (SO42-): ≤200 mg/kg
• Reduction residue: ≤0.01%
• Linear Formula: Hg(NO3)2 · H2O

DETAILS

Sigma Aldrich - 516953

Application
Reagent for oxymercuration; amidomercuration; cyclopropanecleavage; glycosylation
Features and Benefits
Meets A.C.S. reagent specifications.
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 230421

Packaging
50, 250 g in glass bottle
Application
Increasing interest in solid state NMR of heavy-metal nuclei results in the preparation of several Hg-thiocyanate and selenocyanate compounds as potential models.1