dilithium(1+) ion tetrachloromanganesediuide

• ChemBase ID: 138660
• Molecular Formular: Cl4Li2Mn
• Molecular Mass: 210.632049
• Monoisotopic Mass: 208.84546492
• SMILES: [Li+].[Li+].Cl[Mn-2](Cl)(Cl)Cl
• Canonical SMILES: Cl[Mn-2](Cl)(Cl)Cl.[Li+].[Li+]
• InChI: InChI=1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4
• InChIKey: VJOUQNFWQPCDPE-UHFFFAOYSA-J

NAMES AND DATABASE IDS

Names

• IUPAC name: dilithium(1+) ion tetrachloromanganesediuide
• IUPAC Traditional name: dilithium(1+) ion tetrachloromanganesediuide
• Synonyms: Manganese(II) chloride bis(lithium chloride) complex solution; Lithium tetrachloromanganate(II) solution; Lithium chloromanganate(II); Lithium manganese chloride; Lithium tetrachloromanganate(II) solution; Manganese(II) chloride bis(lithium chloride) complex solution; 氯化锰(II)双(氯化锂)络合物 溶液; 四氯锰酸(II)锂 溶液; 四氯锰酸(II)锂 溶液; 氯化锂锰; 氯锰酸(II)锂; 氯化锰(II)双(氯化锂)络合物 溶液

Database IDs

• CAS Number: 57384-24-4
• MDL Number: MFCD00192059
• PubChem SID: 162232911
• PubChem CID: 11805976

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.788
• LogD (pH = 7.4): 1.788
• Log P: 1.788
• Molar Refractivity: 24.5452 cm^3
• Polarizability: 12.276724 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 67 °C
• Flash Point: 1 °F; -17 °C; -19 °C; -2 °F
• Density: 0.956 g/mL at 25 °C; 0.976 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Flammable (F); Harmful (Xn)
• UN Number: 1993; 2056
• German water hazard class: 3
• Hazard Class: 3
• Packing Group: 2
• Risk Statements: 11-19-22-36/37/38
• Safety Statements: 16-26-33-36
• RID/ADR: UN 1993 3/PG 2; UN 2056 3/PG 2

Product Information

• Concentration: 0.5 M in THF
• Linear Formula: Li2MnCl4

DETAILS

Sigma Aldrich - 718114

Packaging
100 mL in Sure/Seal™
Application
Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant1Reactant for:
• Transmetalation reactions2
• Nickel-imidazolium carbene-catalyzed coupling reactions3Reagent for the preparation of Rieke manganese4