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12635-27-7 molecular structure
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alumane nickel

ChemBase ID: 138573
Molecular Formular: AlNi
Molecular Mass: 85.674938
Monoisotopic Mass: 84.91688153
SMILES and InChIs

SMILES:
[AlH3].[Ni]
Canonical SMILES:
[AlH3].[Ni]
InChI:
InChI=1S/Al.Ni
InChIKey:
NPXOKRUENSOPAO-UHFFFAOYSA-N

Cite this record

CBID:138573 http://www.chembase.cn/molecule-138573.html

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NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
alumane nickel
IUPAC Traditional name
alumane nickel
Synonyms
Raney Ni
Nickel sponge
Raney®-Nickel
Aluminum-nickel catalyst
Nickel aluminum
Nickel-aluminum alloy
Raney®-Nickel alloy
Aluminum-nickel alloy
Aluminum Nickel
海绵镍
Raney®-镍
铝镍合金催化剂
镍铝
Raney® 镍合金
镍铝合金
铝镍合金
CAS Number
12635-27-7
12003-78-0
7440-02-0
EC Number
234-439-6
MDL Number
MFCD00167392
PubChem SID
24886372
24853255
24873469
24873470
162232826
24873472
24853256
PubChem CID
6336846

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
Log P 0.472  Molar Refractivity 2.4 cm3
Polarizability 3.2326243 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five true 
LogD (pH = 5.5) 0.472  LogD (pH = 7.4) 0.472 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Apperance
-100+325 Mesh Powder, Intermetallic expand Show data source
Powder expand Show data source
slurry expand Show data source
Density
3.46 g/mL at 25 °C(lit.) expand Show data source
pH
8.5-12.0 expand Show data source
European Hazard Symbols
Flammable Flammable (F) expand Show data source
Toxic Toxic (T) expand Show data source
X expand Show data source
Harmful Harmful (Xn) expand Show data source
UN Number
1378 expand Show data source
3089 expand Show data source
UN3089 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
German water hazard class
2 expand Show data source
3 expand Show data source
Hazard Class
4.1 expand Show data source
4.2 expand Show data source
Packing Group
2 expand Show data source
II expand Show data source
Risk Statements
11-40-43 expand Show data source
15-40-43 expand Show data source
17-40-43-48/23 expand Show data source
40-42/43 expand Show data source
Safety Statements
15-26-28-36/37/39 expand Show data source
23-36/37 expand Show data source
36/37 expand Show data source
36/37-43 expand Show data source
36/37-60 expand Show data source
TSCA Listed
expand Show data source
GHS Pictograms
GHS02 expand Show data source
GHS07 expand Show data source
GHS08 expand Show data source
GHS Signal Word
Danger expand Show data source
GHS Hazard statements
H228-H317-H351 expand Show data source
H228-H351-H317 expand Show data source
H250-H317-H351-H372 expand Show data source
H250-H317-H351-H372-H412 expand Show data source
H334-H317-H351 expand Show data source
GHS Precautionary statements
P210-P241-P302+P352-P321-P405-P501A expand Show data source
P210-P280 expand Show data source
P222-P231-P273-P280-P314-P422 expand Show data source
P222-P231-P280-P314-P422 expand Show data source
P285-P261-P302+P352-P321-P405-P501A expand Show data source
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges expand Show data source
RID/ADR
UN 1378 4.2/PG 2 expand Show data source
UN 3089 4.1/PG 2 expand Show data source
Purity
50% Al basis expand Show data source
50% Ni basis expand Show data source
99.0% min (metals basis) expand Show data source
Concentration
in H2O expand Show data source
Grade
purum expand Show data source
Compostion
Al-Ni, 50:50 wt. % expand Show data source
Ni, ≥89% expand Show data source
Impurities
6-9% Al expand Show data source
Linear Formula
AlNi expand Show data source
Empirical Formula (Hill Notation)
AlNi expand Show data source

DETAILS

DETAILS

Sigma Aldrich Sigma Aldrich
Sigma Aldrich - 221651 external link
Application
Raney-type alloy for the preparation of Raney® Nickel catalyst. ,
Catalyst for:
• Reduction reactions1
• Reductive dehalogenation and ring saturation reactions2Used for:
• Preparation of aluminum oxy-hydrate supported NiAl skeleton catalyst for hydrogenation reactions3
Packaging
100 g in glass bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
Sigma Aldrich - 221678 external link
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Suitable as a hydrogenation catalyst for aromatic, olefin, nitrile and nitro group reductions.
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
Sigma Aldrich - 510068 external link
Application
Useful as a selective reducing agent for hydrogenation of organic compounds
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
Sigma Aldrich - 510033 external link
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
Sigma Aldrich - 510041 external link
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
Sigma Aldrich - 72240 external link
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

REFERENCES

REFERENCES

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PATENTS

PATENTS

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INTERNET

INTERNET

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