alumane nickel

• ChemBase ID: 138573
• Molecular Formular: AlNi
• Molecular Mass: 85.674938
• Monoisotopic Mass: 84.91688153
• SMILES: [AlH3].[Ni]
• Canonical SMILES: [AlH3].[Ni]
• InChI: InChI=1S/Al.Ni
• InChIKey: NPXOKRUENSOPAO-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: alumane nickel
• IUPAC Traditional name: alumane nickel
• Synonyms: Raney Ni; Nickel sponge; Raney®-Nickel; Aluminum-nickel catalyst; Nickel aluminum; Nickel-aluminum alloy; Raney®-Nickel alloy; Aluminum-nickel alloy; Aluminum Nickel; 海绵镍; Raney®-镍; 铝镍合金催化剂; 镍铝; Raney® 镍合金; 镍铝合金; 铝镍合金

Database IDs

• CAS Number: 12635-27-7; 12003-78-0; 7440-02-0
• EC Number: 234-439-6
• MDL Number: MFCD00167392
• PubChem SID: 162232826; 24853255; 24873472; 24853256; 24873469; 24873470; 24886372
• PubChem CID: 6336846

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• Log P: 0.472
• Molar Refractivity: 2.4 cm^3
• Polarizability: 3.2326243 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true
• LogD (pH = 5.5): 0.472
• LogD (pH = 7.4): 0.472

PROPERTIES

Physical Property

• Apperance: -100+325 Mesh Powder, Intermetallic; Powder; slurry
• Density: 3.46 g/mL at 25 °C(lit.)
• pH: 8.5-12.0

Safety Information

• European Hazard Symbols: Flammable (F); Toxic (T); X; Harmful (Xn)
• UN Number: 1378; 3089; UN3089
• German water hazard class: 2; 3
• Hazard Class: 4.1; 4.2
• Packing Group: 2; II
• Risk Statements: 11-40-43; 15-40-43; 17-40-43-48/23; 40-42/43
• Safety Statements: 15-26-28-36/37/39; 23-36/37; 36/37; 36/37-43; 36/37-60
• TSCA Listed: 是
• GHS Pictograms: GHS02; GHS07; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H317-H351; H228-H351-H317; H250-H317-H351-H372; H250-H317-H351-H372-H412; H334-H317-H351
• GHS Precautionary statements: P210-P241-P302+P352-P321-P405-P501A; P210-P280; P222-P231-P273-P280-P314-P422; P222-P231-P280-P314-P422; P285-P261-P302+P352-P321-P405-P501A
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1378 4.2/PG 2; UN 3089 4.1/PG 2

Product Information

• Purity: 50% Al basis; 50% Ni basis; 99.0% min (metals basis)
• Concentration: in H2O
• Grade: purum
• Compostion: Al-Ni, 50:50 wt. %; Ni, ≥89%
• Impurities: 6-9% Al
• Linear Formula: AlNi
• Empirical Formula (Hill Notation): AlNi

DETAILS

Sigma Aldrich - 221651

Application
Raney-type alloy for the preparation of Raney® Nickel catalyst. ,
Catalyst for:
• Reduction reactions1
• Reductive dehalogenation and ring saturation reactions2Used for:
• Preparation of aluminum oxy-hydrate supported NiAl skeleton catalyst for hydrogenation reactions3
Packaging
100 g in glass bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sigma Aldrich - 221678

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Suitable as a hydrogenation catalyst for aromatic, olefin, nitrile and nitro group reductions.
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sigma Aldrich - 510068

Application
Useful as a selective reducing agent for hydrogenation of organic compounds
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sigma Aldrich - 510033

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100, 500 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sigma Aldrich - 510041

Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
Packaging
100 g in poly bottle
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.

Sigma Aldrich - 72240

Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.