lithium(1+) ion tetrachlorogallanuide

• ChemBase ID: 138386
• Molecular Formular: Cl4GaLi
• Molecular Mass: 218.476
• Monoisotopic Mass: 215.81698827
• SMILES: [Li+].Cl[Ga-](Cl)(Cl)Cl
• Canonical SMILES: Cl[Ga-](Cl)(Cl)Cl.[Li+]
• InChI: InChI=1S/4ClH.Ga.Li/h4*1H;;/q;;;;+3;+1/p-4
• InChIKey: KMBVSAMILLNTNQ-UHFFFAOYSA-J

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion tetrachlorogallanuide
• IUPAC Traditional name: lithium(1+) ion tetrachlorogallanuide
• Synonyms: Lithium tetrachlorogallate; 四氯镓酸锂

Database IDs

• CAS Number: 15955-98-3
• MDL Number: MFCD00274652
• PubChem SID: 162232642; 24868607
• PubChem CID: 16701583

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.538
• LogD (pH = 7.4): 2.538
• Log P: 2.538
• Molar Refractivity: 24.5452 cm^3
• Polarizability: 12.78808 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: beads; powder
• Melting Point: 175 °C(lit.)

Safety Information

• European Hazard Symbols: Corrosive (C)
• UN Number: 3260
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 14-20/21/22-34
• Safety Statements: 22-26-27-36/37/39-45
• GHS Pictograms: GHS05; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H302-H312-H314-H332
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3260 8/PG 2
• Supplemental Hazard Statements: Reacts violently with water.
• Storage Temperature: 2-8°C

Product Information

• Purity: ≥99.99% trace metals basis; 99.99% trace metals basis
• Grade: anhydrous
• Particle Size: -10 mesh
• Linear Formula: LiGaCl4

DETAILS

Sigma Aldrich - 736317

Packaging
5 g in glass bottle

Sigma Aldrich - 451150

Application
Shows promise as the electrolyte in rechargeable batteries.1,2