sodiumamine

• ChemBase ID: 137152
• Molecular Formular: H2NNa
• Molecular Mass: 39.01235
• Monoisotopic Mass: 39.00849335
• SMILES: N[Na]
• Canonical SMILES: N[Na]
• InChI: InChI=1S/H2N.Na/h1H2;/q-1;+1
• InChIKey: ODZPKZBBUMBTMG-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: sodiumamine
• IUPAC Traditional name: sodiumamine
• Synonyms: Sodium amide; 氨基钠

Database IDs

• CAS Number: 7782-92-5
• EC Number: 231-971-0
• MDL Number: MFCD00011117
• PubChem SID: 162231417; 24857541; 24857437; 24852506; 24867092
• PubChem CID: 24533

CALCULATED PROPERTIES

• H Acceptors: 1
• H Donor: 1
• LogD (pH = 5.5): -2.078919
• LogD (pH = 7.4): -1.8428185
• Log P: -1.8388
• Molar Refractivity: 5.2841 cm^3
• Polarizability: 3.904275 Å^3
• Polar Surface Area: 26.02 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: crystalline
• Melting Point: 210 °C(lit.)
• Boiling Point: 400 °C(lit.)
• Flash Point: 29 °C; 39.2 °F; 4 °C; 84.2 °F

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F); Nature polluting (N)
• UN Number: 1390; 3129
• German water hazard class: 2
• Hazard Class: 4.3
• Packing Group: 1; 2
• Risk Statements: 10-14/15-19-20/21-29-34-50; 14/15-19-29-34-50; 63-11-14/15-19-29-34-48/20-50-65-67
• Safety Statements: 26-36/37/39-43-45-61; 26-36/37/39-43-45-61-62
• GHS Pictograms: GHS02; GHS05; GHS07; GHS08; GHS09
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H261-H304-H314-H336-H361d-H373-H400; H226-H261-H314-H400; H261-H314-H400
• GHS Precautionary statements: P210-P231 + P232-P261-P273-P280-P422; P231 + P232-P273-P280-P305 + P351 + P338-P310-P422
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1390 4.3/PG 2; UN 3129 4.3/PG 1; UN 3129 4.3/PG 2
• Supplemental Hazard Statements: Contact with water liberates toxic gas., May form explosive peroxides.

Product Information

• Purity: ≥95.0% (T); 95%; 98%
• Concentration: 50 wt. % suspension in toluene; 50 wt. % suspension in xylenes
• Grade: CP; hydrogen-storage grade; purum
• Linear Formula: NaNH2

DETAILS

Sigma Aldrich - 208329

Packaging
50, 250 g in glass bottle
Application
Reagent for: Synthesis of allylic amines and amides1 Synthesis of antibacterials2 Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 432504

Packaging
25, 100 g in glass bottle
Application
Reagent for synthesis of: Allylic amines and amides1 Antibacterials2 Reagent for: Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 291587

Packaging
100, 750 g in glass bottle
Application
Reagent for: Synthesis of allylic amines and amides1 Synthesis of antibacterials2 Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 686042

Analysis Note
Hydrogen content, XRD plots and metal purity data are available upon request.
Packaging
10 g in glass bottle