trichlorocerium

• ChemBase ID: 137020
• Molecular Formular: CeCl3
• Molecular Mass: 246.475
• Monoisotopic Mass: 244.81199604
• SMILES: Cl[Ce](Cl)Cl
• Canonical SMILES: Cl[Ce](Cl)Cl
• InChI: InChI=1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
• InChIKey: VYLVYHXQOHJDJL-UHFFFAOYSA-K

NAMES AND DATABASE IDS

Names

• IUPAC name: trichlorocerium
• IUPAC Traditional name: cerium chloride
• Synonyms: Cerium trichloride; Cerous chloride; Cerium(III) chloride; 氯化亚铈; 氯化铈(III)

Database IDs

• CAS Number: 7790-86-5
• EC Number: 232-227-8
• MDL Number: MFCD00010929
• PubChem SID: 24866857; 162231286; 24857966
• PubChem CID: 161282

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.9035
• LogD (pH = 7.4): 1.9035
• Log P: 1.9035
• Molar Refractivity: 18.4089 cm^3
• Polarizability: 12.935312 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: beads
• Melting Point: 848 °C(lit.)
• Density: 3.97 g/mL at 25 °C(lit.)

Safety Information

• RTECS: FK5075000
• European Hazard Symbols: Irritant (Xi)
• German water hazard class: 2
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves

Product Information

• Purity: ≥99%; ≥99.9%; ≥99.99% trace metals basis; 99.9%
• Grade: anhydrous
• Particle Size: -10 mesh
• Empirical Formula (Hill Notation): CeCl3

DETAILS

Sigma Aldrich - 450758

Packaging
Packaged under argon in ampules
Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.1

Sigma Aldrich - 298190

Packaging
50 g in ampule
Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.1

Sigma Aldrich - 429406

Packaging
5, 25 g in ampule
Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.1

Sigma Aldrich - 450731

Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.1