bromo(methyl)magnesium

• ChemBase ID: 136955
• Molecular Formular: CH3BrMg
• Molecular Mass: 119.24352
• Monoisotopic Mass: 117.9268538
• SMILES: C[Mg]Br
• Canonical SMILES: C[Mg]Br
• InChI: InChI=1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
• InChIKey: AVFUHBJCUUTGCD-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: bromo(methyl)magnesium
• IUPAC Traditional name: bromo(methyl)magnesium
• Synonyms: Methylmagnesium bromide solution; 甲基溴化镁 溶液

Database IDs

• CAS Number: 75-16-1
• MDL Number: MFCD00000041
• Beilstein Number: 3535220
• PubChem SID: 24851403; 162231222; 24858252; 24857032
• PubChem CID: 6349

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.6162
• LogD (pH = 7.4): 0.6162
• Log P: 0.6162
• Molar Refractivity: 14.5153 cm^3
• Polarizability: 7.4795656 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 78-80 °C/760 mmHg
• Flash Point: 1.4 °F; 10.4 °F; -12 °C; -17 °C; 25 °C; -40 °C; -40 °F; 77 °F
• Density: 0.856 g/mL at 25 °C; 1.018 g/mL at 25 °C; 1.02 g/mL at 20 °C; 1.035 g/mL at 25 °C; 1.117 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F); Highly flammable (F+)
• UN Number: 1928; 3399
• German water hazard class: 1; 2
• Hazard Class: 4.3
• Packing Group: 1; 2
• Risk Statements: 10-14/15-34-37-52/53; 11-14/15-19-22-34-67; 11-14/15-19-34; 11-14-19-22-34-67; 12-14-19-22-34-66-67; 63-11-14/15-34-48/20-65-67
• Safety Statements: 16-26-36/37/39-43-45; 16-26-36/37/39-43-45-62; 16-26-36/37/39-45; 26-36/37/39-43-45-61; 9-16-26-45
• GHS Pictograms: GHS02; GHS05; GHS07; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H302-H314-H336; H225-H260-H304-H314-H336-H361d-H373; H225-H261-H314; H226-H260-H314-H335-H412
• GHS Precautionary statements: P210-P222-P223-P231 + P232-P370 + P378-P422; P210-P223-P231 + P232-P261-P370 + P378-P422; P210-P231 + P232-P280-P305 + P351 + P338-P310-P422; P223-P231 + P232-P261-P273-P370 + P378-P422
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1928 4.3/PG 1; UN 3399 4.3/PG 1; UN 3399 4.3/PG 2
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.; Reacts violently with water.

Product Information

• Concentration: ~3 M in diethyl ether; ~3.2 M in 2-methyltetrahydrofuran; 1.0 M in dibutyl ether; 1.4 M in THF: toluene (1:3); 3.0 M in diethyl ether; 35 % (w/w)
• Grade: purum
• Linear Formula: CH3MgBr

DETAILS

Sigma Aldrich - 703583

Packaging
100, 800 mL in Sure/Seal™
Legal Information
Product of Rockwood Lithium

Sigma Aldrich - 302430

Packaging
100, 800 mL in Sure/Seal™

Sigma Aldrich - 257087

Packaging
200 mL in Sure-Pac™
Recommended products
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.

Sigma Aldrich - 282235

Packaging
100, 800 mL in Sure/Seal™

Sigma Aldrich - 189898

Packaging
4×25, 50, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.