dichloromanganese

• ChemBase ID: 132881
• Molecular Formular: Cl2Mn
• Molecular Mass: 125.844049
• Monoisotopic Mass: 124.87575046
• SMILES: Cl[Mn]Cl
• Canonical SMILES: Cl[Mn]Cl
• InChI: InChI=1S/2ClH.Mn/h2*1H;/q;;+2/p-2
• InChIKey: GLFNIEUTAYBVOC-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: dichloromanganese
• IUPAC Traditional name: manganese(II) chloride
• Synonyms: Manganese atomic spectroscopy standard concentrate 10.00 g Mn; Additive Screening Solution 26/Fluka kit no 78374; Manganese(II) chloride solution; Manganese(II) chloride 0.1 M solution; Manganese standard solution; Manganese atomic spectroscopy standard concentrate 1.00 g Mn; Manganese dichloride; Sacchite; Manganese(II) chloride; Manganese(II) chloride solution; 二氯化锰(II) 溶液; 锰标准浓缩液 10.00g Mn; Manganese standard solution; 锰原子光谱分析标准浓缩液 1.00g Mn; 氯化亚锰; 二氯化锰(II) 溶液

Database IDs

• CAS Number: 7773-01-5
• EC Number: 231-869-6
• MDL Number: MFCD00011114
• PubChem SID: 162227158; 24845346; 24896693; 24859717; 24868596; 24865907; 24845453; 24854686; 24866861; 24872316
• PubChem CID: 24480

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.819
• LogD (pH = 7.4): 0.819
• Log P: 0.819
• Molar Refractivity: 12.2726 cm^3
• Polarizability: 7.765818 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: H2O: soluble
• Apperance: beads; flakes; powder and chunks
• Melting Point: 652 °C(lit.)
• Density: 1.01 g/mL at 20 °C; 2.98 g/mL at 25 °C(lit.)

Safety Information

• RTECS: OO9625000
• European Hazard Symbols: Harmful (Xn)
• UN Number: 3288
• German water hazard class: 1; nwg
• Hazard Class: 6.1
• Packing Group: 3
• Risk Statements: 22-52
• GHS Pictograms: GHS06; GHS07; GHS09
• GHS Signal Word: Danger; Warning
• GHS Hazard statements: H301-H411; H302-H412; H412
• GHS Precautionary statements: P273; P273-P301 + P310
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves; Eyeshields, Faceshields, Gloves; Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• RID/ADR: UN 3288 6.1/PG 3
• Storage Temperature: 2-8°C

Product Information

• Purity: ≥99% trace metals basis; 97%; 98%; 99.99% trace metals basis; 99.999% trace metals basis
• Concentration: 1 mg/mL Mn+2; 1.00 M±0.01 M; 10.00 g/L; 1000 ppm Mn+2
• Grade: anhydrous; for molecular biology
• Particle Size: -10 mesh
• Suitability: suitable for atomic absorption spectrometry
• Description: for 1 l standard solution (content 1.00 g/l)
• Cation Traces: heavy metals (as Pb): ≤5 ppm
• Foreign Activity: DNase, Exonuclease; NICKase, Endonuclease; and protease, none detected
• Sterility: 0.2 μm filtered
• Shelf Life: (limited shelf life, expiry date on the label)
• Quality: ampule
• Linear Formula: MnCl2

DETAILS

Sigma Aldrich - M1787

Preparation Note
Prepared in 18 megohm water

Sigma Aldrich - 416479

Packaging
2 kg in poly drum
500 g in glass bottle
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.2

Sigma Aldrich - 429449

Packaging
5, 25 g in ampule
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.2

Sigma Aldrich - 450995

Packaging
5, 25 g in ampule
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.2

Sigma Aldrich - 244589

Packaging
10 g in glass bottle
50 g in poly bottle
250 g in glass bottle
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.2

Sigma Aldrich - 328146

Packaging
2 kg in glass bottle
25, 500 g in glass bottle
Application
A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.1 Also used in the formation of an active Mn(0) speciesuseful for radical cyclization reactions.2

Sigma Aldrich - 02654

Preparation Note
prepared with MnCl2.4H2O and H2O

Sigma Aldrich - 03357

Preparation Note
prepared with MnCl2.4H2O and H2O