tetrachlorovanadium

• ChemBase ID: 130121
• Molecular Formular: Cl4V
• Molecular Mass: 192.7535
• Monoisotopic Mass: 190.81937022
• SMILES: Cl[V](Cl)(Cl)Cl
• Canonical SMILES: Cl[V](Cl)(Cl)Cl
• InChI: InChI=1S/4ClH.V/h4*1H;/q;;;;+4/p-4
• InChIKey: JTJFQBNJBPPZRI-UHFFFAOYSA-J

NAMES AND DATABASE IDS

Names

• IUPAC name: tetrachlorovanadium
• IUPAC Traditional name: vanadium tetrachloride
• Synonyms: Vanadium tetrachloride; Vanadium(IV) chloride; Vanadium tetrachloride; 氯化钒(IV)

Database IDs

• CAS Number: 7632-51-1
• EC Number: 231-561-1
• MDL Number: MFCD00061343
• PubChem SID: 162224406; 24862677
• PubChem CID: 24273
• Chemspider ID: 19956660
• Wikipedia Title: Vanadium_tetrachloride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.538
• LogD (pH = 7.4): 2.538
• Log P: 2.538
• Molar Refractivity: 24.5452 cm^3
• Polarizability: 12.256031 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: chlorocarbons, hydrochloric acid; decomposes in water; diethyl ether: slightly soluble; ethanol: slightly soluble
• Apperance: bright red liquid, moisture sensitive; liquid
• Melting Point: -28 °C; -28 °C(lit.)
• Boiling Point: 154 °C; 154 °C(lit.)
• Density: 1.816 g/cm^3, liquid; 1.816 g/mL at 25 °C(lit.)
• Vapor Pressure: 7.9 Pa

Safety Information

• RTECS: YW2625000
• European Hazard Symbols: Toxic (T)
• UN Number: 2444
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 1
• Risk Statements: 14-23/24/25-34
• Safety Statements: 26-27-36/37/39-45
• EU Index: Not listed
• GHS Pictograms: GHS05; GHS06
• GHS Signal Word: Danger
• Main Hazard: oxidizer; hydrolyzes to release HCl
• NFPA704:
  

  0

  3

  2

  W
• GHS Hazard statements: H301 + H311 + H331-H314
• GHS Precautionary statements: P261-P280-P301 + P310-P305 + P351 + P338-P310
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2444 8/PG 1
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Linear Formula: VCl4

DETAILS

Sigma Aldrich - 366617

Packaging
100 g in Sure/Seal™