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603-32-7 molecular structure
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triphenylarsane

ChemBase ID: 130025
Molecular Formular: C18H15As
Molecular Mass: 306.2333
Monoisotopic Mass: 306.03897148
SMILES and InChIs

SMILES:
c1ccc(cc1)[As](c1ccccc1)c1ccccc1
Canonical SMILES:
c1ccc(cc1)[As](c1ccccc1)c1ccccc1
InChI:
InChI=1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChIKey:
BPLUKJNHPBNVQL-UHFFFAOYSA-N

Cite this record

CBID:130025 http://www.chembase.cn/molecule-130025.html

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NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
triphenylarsane
IUPAC Traditional name
triphenylarsine
Synonyms
Arsinetriphenyl
Triphenylarsine
triphenylarsane
Tribenzenidoarsenic
Triphenylarsine
Triphenylarsine
三苯胂
三苯基胂
CAS Number
603-32-7
EC Number
210-032-9
MDL Number
MFCD00002994
Beilstein Number
1842037
PubChem SID
162224310
24872773
24900510
PubChem CID
11773
Chemspider ID
11280
Wikipedia Title
Triphenylarsine

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
LogD (pH = 5.5) 5.5566  LogD (pH = 7.4) 5.5566 
Log P 5.5566  Molar Refractivity 76.4229 cm3
Polarizability 33.31161 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five false 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Apperance
Colourless solid expand Show data source
solid expand Show data source
Melting Point
58 - 61°C expand Show data source
58-61 °C(lit.) expand Show data source
60 - 62°C expand Show data source
60-62°C expand Show data source
Boiling Point
175°C (at 1.5 mmHg) expand Show data source
360°C expand Show data source
Flash Point
265°C(509°F) expand Show data source
Density
1.395 g cm-3 expand Show data source
Hydrophobicity(logP)
5.377 expand Show data source
RTECS
CH7942500 expand Show data source
CH8942500 expand Show data source
European Hazard Symbols
Nature polluting Nature polluting (N) expand Show data source
Toxic Toxic (T) expand Show data source
UN Number
3465 expand Show data source
UN3465 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
German water hazard class
3 expand Show data source
Hazard Class
6.1 expand Show data source
Packing Group
2 expand Show data source
II expand Show data source
Risk Statements
23/25-50/53 expand Show data source
R23/25, R50/53 expand Show data source
Safety Statements
20/21-28-45-60-61 expand Show data source
20/21-28a-45-60-61 expand Show data source
S20/21, S28, S45, S60, S61 expand Show data source
TSCA Listed
expand Show data source
GHS Pictograms
GHS06 expand Show data source
GHS09 expand Show data source
GHS Signal Word
Danger expand Show data source
GHS Hazard statements
H301-H331-H400-H410 expand Show data source
H301-H331-H410 expand Show data source
GHS Precautionary statements
P261-P273-P301 + P310-P311-P501 expand Show data source
P261-P301+P310-P321-P304+P340-P405-P501A expand Show data source
RID/ADR
UN 3465 6.1/PG 2 expand Show data source
Purity
95% expand Show data source
97% expand Show data source
98% expand Show data source
99.99% trace metals basis expand Show data source
Linear Formula
(C6H5)3As expand Show data source

DETAILS

DETAILS

Wikipedia Wikipedia Sigma Aldrich Sigma Aldrich
Sigma Aldrich - T81906 external link
Packaging
5, 25, 100 g in glass bottle
Sigma Aldrich - 492736 external link
General description
Atomic number of base material: 33 Arsenic
Packaging
5 g in poly bottle

REFERENCES

REFERENCES

From Suppliers Google Scholar IconGoogle Scholar PubMed iconPubMed Google Books IconGoogle Books
  • • Can be cleaved to sodium diphenylarsenide by Na metal. A mole of PhNa is also produced, but can be selectively destroyed by protonation with NH4Br: Chem. Ber., 100, 1230 (1967). For use in the preparation of chelating ligands, see: Synthesis, 350 (1979). Similarly, Li metal gives Li diphenylarsenide: J. Org. Chem., 32, 2627 (1967). For a review of the chemistry of metal arsenides, see: Synthesis, 328 (1974).
  • • Preferred to phosphines as a ligand in certain metal-catalyzed coupling reactions, e.g. in the Pd catalyzed Stille coupling of aryl stannanes with aryl halides: Tetrahedron Lett., 36, 2191 (1995), of silylated allylic stannanes with alkyl halides: J. Org. Chem., 60, 4647 (1995), the Pd catalyzed homocoupling of organostannanes: Synth. Commun., 27, 641 (1997), the Pd catalyzed coupling of aryl- or alkynylzinc chlorides with alkenyl halides: Synlett, 344 (1995), or the Suzuki coupling of arylboronic acids with sensitive halides: Org. Synth., 75, 69 (1997).
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PATENTS

PATENTS

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INTERNET

INTERNET

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