dimethyl[tris(dimethylamino)titanio]amine

• ChemBase ID: 129802
• Molecular Formular: C8H24N4Ti
• Molecular Mass: 224.16996
• Monoisotopic Mass: 224.14804309
• SMILES: CN(C)[Ti](N(C)C)(N(C)C)N(C)C
• Canonical SMILES: CN([Ti](N(C)C)(N(C)C)N(C)C)C
• InChI: InChI=1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4
• InChIKey: MNWRORMXBIWXCI-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: dimethyl[tris(dimethylamino)titanio]amine
• IUPAC Systematic name: Dimethyl[tris(dimethylamino)titanio]amine
• IUPAC Traditional name: dimethyl[tris(dimethylamino)titanio]amine
• Synonyms: Titanium(IV) dimethylamide; Tetrakis(dimethylamido)titanium; TDMAT; Tetrakis(dimethylamino)titanium(IV); Tetrakis(dimethylamido)titanium(IV); 四(二甲基氨基)钛(IV); 四(二甲基胺基)钛(IV)

Database IDs

• CAS Number: 3275-24-9
• EC Number: 221-904-3
• MDL Number: MFCD00014861
• PubChem SID: 24885015; 162224090; 24870618
• PubChem CID: 123185
• Chemspider ID: 13870283
• Wikipedia Title: Tetrakis(dimethylamido)titanium

CALCULATED PROPERTIES

• H Acceptors: 4
• H Donor: 0
• LogD (pH = 5.5): -4.5969706
• LogD (pH = 7.4): -4.1305056
• Log P: -0.8472
• Molar Refractivity: 55.5736 cm^3
• Polarizability: 25.02209 Å^3
• Polar Surface Area: 12.96 Å^2
• Rotatable Bonds: 4
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: reacts with water
• Apperance: liquid; yellow liquid
• Boiling Point: 50 °C at 0.05mmHg; 50 °C/0.5 mmHg(lit.)
• Flash Point: -22 °F; -30 °C
• Density: 0.947 g/cm3; 0.947 g/mL at 25 °C(lit.)

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F)
• UN Number: 2924; 3398; 3398
• German water hazard class: 3
• Hazard Class: 4.3
• Packing Group: 1
• Risk Statements: 11-14-34
• Safety Statements: 16 - 26 - 36/37/39 - 43 - 45; 16-26-36/37/39-43-45
• GHS Pictograms: GHS02; GHS05
• GHS Signal Word: Danger
• NFPA704:
  

  3

  3

  2
• GHS Hazard statements: H225-H260-H314
• GHS Precautionary statements: P210-P223-P231 + P232-P280-P370 + P378-P422
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 3398 4.3/PG 1
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Purity: 99.999%
• Quality Level: HITECH
• Linear Formula: [(CH3)2N]4Ti

DETAILS

Sigma Aldrich - 669008

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Precursor for the deposition of titanium dioxide by atmoic layer deposition with water.1
General description
Atomic number of base material: 22 Titanium
Packaging
25 g in ss cylinder
Protocols & Applications
Precursors Packaged for Depositions Systems

Sigma Aldrich - 469858

General description
Please inquire for bulk quantity, pricing, and packaging options.
Packaging
5, 25 g in ampule
Application
Precursor to titanium nitride (TiN) thin films by organometallic chemical vapor deposition (OMCVD).1