sodium alumanuide

• ChemBase ID: 129503
• Molecular Formular: AlNa
• Molecular Mass: 49.971308
• Monoisotopic Mass: 49.97130791
• SMILES: [Na+].[AlH3-]
• Canonical SMILES: [Na+].[AlH3-]
• InChI: InChI=1S/Al.Na/q-1;+1
• InChIKey: BVVXRBADTGAXIA-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: sodium alumanuide
• IUPAC Traditional name: sodium alumanuide
• Synonyms: Sodium tetrahydroaluminate; Sodium aluminium hydride; Sodium aluminum hydride solution; Sodium aluminum hydride; 氢化铝钠 溶液; 氢化铝钠

Database IDs

• CAS Number: 13770-96-2
• EC Number: 237-400-1
• MDL Number: MFCD00192443
• PubChem SID: 24885693; 24861919
• PubChem CID: 26266
• Wikipedia Title: Sodium_aluminium_hydride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): -0.77
• LogD (pH = 7.4): -0.77
• Log P: -0.77
• Molar Refractivity: 0.0 cm^3
• Polarizability: 2.0172503 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: soluble in THF
• Apperance: White crystalline solid
• Melting Point: 183°C (decomp)
• Flash Point: -22 °C; -7 °F (-22 °C); -7.6 °F
• Density: 0.905 g/mL at 25 °C; 1.24 g/cm^3

Safety Information

• RTECS: BD0180000
• European Hazard Symbols: Corrosive (C); Flammable (F); Irritant (Xi)
• UN Number: 2835; 3399
• German water hazard class: 1
• Hazard Class: 4.3
• Packing Group: 1; 2
• Risk Statements: 11-14/15-19-36/37/38; 14/15-22-34
• Safety Statements: 16-26-43; 7/8-26-36/37/39-43-45
• GHS Pictograms: GHS02; GHS05; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H261-H314-H335; H261-H302-H314
• GHS Precautionary statements: P210-P231 + P232-P261-P280-P305 + P351 + P338-P422; P231 + P232-P280-P305 + P351 + P338-P310-P422
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2835 4.3/PG 2; UN 3399 4.3/PG 1
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.; Reacts violently with water.

Product Information

• Purity: 90%; 93%
• Concentration: 1 M in THF
• Grade: hydrogen-storage grade; technical grade
• Linear Formula: NaAlH4

DETAILS

Sigma Aldrich - 698865

General description
Atomic number of base material: 11
Packaging
1 L in Sure/Seal™
Protocols & Applications
Sodium Aluminium Hydride for Energy Applications

Sigma Aldrich - 685984

Analysis Note
Hydrogen content, XRD plots and metal purity data are available upon request.
General description
Atomic number of base material: 11
Packaging
10 g in glass bottle
Protocols & Applications
Sodium Aluminium Hydride for Energy Applications

Sigma Aldrich - 357472

Packaging
25 g in glass bottle
Application
Reactant used for hydrogen storage1,2