lithium(1+) ion tetrachloroalumanuide

• ChemBase ID: 128091
• Molecular Formular: AlCl4Li
• Molecular Mass: 175.734538
• Monoisotopic Mass: 173.8729539
• SMILES: [Li+].Cl[Al-](Cl)(Cl)Cl
• Canonical SMILES: Cl[Al-](Cl)(Cl)Cl.[Li+]
• InChI: InChI=1S/Al.4ClH.Li/h;4*1H;/q+3;;;;;+1/p-4
• InChIKey: AQLRWYUVWAYZFO-UHFFFAOYSA-J

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion tetrachloroalumanuide
• IUPAC Traditional name: lithium(1+) ion tetrachloroaluminate(1-)
• Synonyms: Lithium tetrachloroaluminate; lithium aluminium chloride; LAC; Lithium tetrachloroaluminate; 四氯铝酸锂

Database IDs

• CAS Number: 14024-11-4
• EC Number: 237-850-9
• MDL Number: MFCD00061440
• PubChem SID: 24868606; 162222405
• PubChem CID: 16700422
• Chemspider ID: 21160220
• Wikipedia Title: Lithium_tetrachloroaluminate

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.988
• LogD (pH = 7.4): 3.988
• Log P: 3.988
• Molar Refractivity: 24.5452 cm^3
• Polarizability: 11.258972 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: beads; powder; white crystals
• Melting Point: ° (decomp)

Safety Information

• European Hazard Symbols: Corrosive (C)
• UN Number: 3260
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 14-20/21/22-34
• Safety Statements: 22-26-27-28.1-36/37/39-45; 22-26-27-28-36/37/39-45
• GHS Pictograms: GHS05; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H302 + H312 + H332-H314
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3260 8/PG 2
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Purity: 99.99%; 99.99% trace metals basis
• Grade: anhydrous
• Particle Size: -10 mesh
• Linear Formula: LiAlCl4

DETAILS

Sigma Aldrich - 429473

Packaging
10 g in ampule
Application
A high-energy, new battery system using only inorganic constituents has been designed where Li and LiCoO2 serve as the electrodes in a LiAlCl4-in-SO2 liquid electrolyte. Has been studied for cell performance characteristics and reaction products of LiAlCl4 and LiGaCl4 in a variety of battery systems.

Sigma Aldrich - 451142

Packaging
5 g in ampule
Application
A high-energy, new battery system using only inorganic constituents has been designed where Li and LiCoO2 serve as the electrodes in a LiAlCl4-in-SO2 liquid electrolyte. Has been studied for cell performance characteristics and reaction products of LiAlCl4 and LiGaCl4 in a variety of battery systems.
Used in studies of electrochemical cell reactions.