trichlorogallane

• ChemBase ID: 127516
• Molecular Formular: Cl3Ga
• Molecular Mass: 176.082
• Monoisotopic Mass: 173.83213104
• SMILES: Cl[Ga](Cl)Cl
• Canonical SMILES: Cl[Ga](Cl)Cl
• InChI: InChI=1S/3ClH.Ga/h3*1H;/q;;;+3/p-3
• InChIKey: UPWPDUACHOATKO-UHFFFAOYSA-K

NAMES AND DATABASE IDS

Names

• IUPAC name: trichlorogallane
• IUPAC Traditional name: gallium trichloride
• Synonyms: Gallium(III) chloride; Trichlorogalliue; Trichlorogallane; Gallium trichloride; Gallium(III) chloride solution; Gallium trichloride; Gallium(III) chloride; 三氯化镓 溶液; 三氯化镓

Database IDs

• CAS Number: 13450-90-3
• EC Number: 236-610-0
• MDL Number: MFCD00011018
• PubChem SID: 24868554; 24866737; 24879288; 162221835
• PubChem CID: 26010
• Chemspider ID: 24229
• Unique Ingredient Identifier: 4Y6GQD4915
• Wikipedia Title: Gallium_trichloride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.9035
• LogD (pH = 7.4): 1.9035
• Log P: 1.9035
• Molar Refractivity: 18.4089 cm^3
• Polarizability: 10.603518 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: soluble in benzene, CCl₄, CS₄; very soluble in water
• Apperance: beads; colorless crystals ; deliquescent; liquid
• Melting Point: 77.9 °C (anhydrous) ; 44.4 °C (hydrate); 78 °C(lit.)
• Boiling Point: 201 °C; 35 °C
• Flash Point: <-25.6 °F; <-32 °C; Non-flammable
• Density: 0.688 g/mL at 25 °C; 2.47 g/cm^3; 2.053 g/cm^3 at melting point; 2.47 g/mL at 25 °C(lit.)
• Vapor Pressure: 1 mmHg ( 48 °C)

Safety Information

• RTECS: LW9100000
• European Hazard Symbols: Corrosive (C); Highly flammable (F+); Nature polluting (N)
• UN Number: 2924; 3260
• German water hazard class: 3
• Hazard Class: 3; 8
• Packing Group: 1; 2
• Risk Statements: 12-14-34-51/53-65-67; 14-34
• Safety Statements: 16-26-36/37/39-45-61-62; 26-27-28.1-36/37/39-45; 26-27-28-36/37/39-45
• EU Index: Not listed
• GHS Pictograms: GHS02; GHS05; GHS07; GHS08; GHS09
• GHS Signal Word: Danger
• NFPA704:
  

  0

  3

  1
• LD50: 4700 mg/kg (rat, oral)
• GHS Hazard statements: H224-H304-H314-H336-H411; H314
• GHS Precautionary statements: P210-P261-P273-P280-P301 + P310-P305 + P351 + P338; P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
• RID/ADR: UN 2924 3/PG 1; UN 3260 8/PG 2
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Purity: ≥99.99%; ≥99.999% trace metals basis; 99.99% trace metals basis
• Concentration: 0.5 M in pentane
• Grade: anhydrous
• Particle Size: -10 mesh
• Linear Formula: GaCl3

DETAILS

Sigma Aldrich - 254193

Features and Benefits
Lower-temperature solvothermal techniques using GaCl3 and NaN31 or Li3N2 result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.
Packaging
product is packed in vials

Sigma Aldrich - 552798

Packaging
25, 100 mL in Sure/Seal™

Sigma Aldrich - 427128

Application
Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.1,2
Features and Benefits
Lower-temperature solvothermal techniques using GaCl3 and NaN33 or Li3N4 result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.
Packaging
5, 25, 100 g in ampule
product is packed in vials

Sigma Aldrich - 450898

Application
Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.1,2
Features and Benefits
Lower-temperature solvothermal techniques using GaCl3 and NaN33 or Li3N4 result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.
Packaging
5, 25, 50 g in ampule
product is packed in vials