dihydrogen hexachloroplatinumdiuide

• ChemBase ID: 126541
• Molecular Formular: Cl6Pt--
• Molecular Mass: 407.796
• Monoisotopic Mass: 404.77790708
• SMILES: Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl
• Canonical SMILES: Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl
• InChI: InChI=1S/6ClH.Pt/h6*1H;/q;;;;;;+4/p-6
• InChIKey: GBFHNZZOZWQQPA-UHFFFAOYSA-H

NAMES AND DATABASE IDS

Names

• IUPAC name: dihydrogen hexachloroplatinumdiuide
• IUPAC Traditional name: dihydrogen hexachloroplatinate(2-)
• Synonyms: Hexachloroplatinic acid; Chloroplatinic acid; Dihydrogen hexachloroplatinate(IV) solution; Dihydrogen hexachloroplatinate(IV) hexahydrate, low nitrate, Premion®; CPA; Chloroplatinic acid; Dihydrogen hexachloroplatinate(IV) hexahydrate; 六氯铂(Ⅳ)酸溶液; 六水合六氯铂(Ⅳ)酸, 低硝酸盐, Premion®; 六水合六氯铂(Ⅳ)酸

Database IDs

• CAS Number: 16941-12-1; 18497-13-7
• EC Number: 241-010-7
• MDL Number: MFCD00149910; MFCD00011330
• Merck Index: 147526
• PubChem SID: 162220873
• PubChem CID: 61859
• Chemspider ID: 55731
• Unique Ingredient Identifier: Q65224GJ7F
• Wikipedia Title: Chloroplatinic_acid

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.837
• LogD (pH = 7.4): 3.837
• Log P: 3.837
• Molar Refractivity: 36.8178 cm^3
• Polarizability: 21.475271 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: highly soluble in water; Soluble in water, alcohol, acetone, ethyl acetate and ether
• Apperance: Crystalline; Liquid; Lump; Reddish brown solid
• Melting Point: 60 °C (333 K); 60°C dec.
• Boiling Point: decomp
• Density: 2.430; 2.431 g/cm^3

Safety Information

• Storage Warning: Hygroscopic
• RTECS: TP1500000; TP1510000
• European Hazard Symbols: Corrosive (C); Nature polluting (N); Toxic (T); Toxic (T)
• UN Number: UN2507; UN3264
• Hazard Class: 8
• Packing Group: III
• Risk Statements: 25-34-42/43-50/53; R25, R34, R42/43
• Safety Statements: 22-26-36/37/39-45; 23-26-36/37/39-45-57; S1/2, S22, S26, S36/37/39, S45
• TSCA Listed: 是
• EU Index: 078-009-00-4
• GHS Pictograms: GHS05; GHS06; GHS08; GHS09
• NFPA704:
  

  0

  2

  1
• GHS Hazard statements: H300-H317-H334-H314-H290; H301-H317-H334-H314-H318-H290-H400-H410
• GHS Precautionary statements: P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A

Product Information

• Purity: 99.9% (metals basis); 99.95% (metals basis), Pt 37.5% min; Pt 20% (cont. Pt)

REFERENCES

• Hydrosilylation catalyst. For use in intramolecular hydrosilylation of an alkyne, see: Tetrahedron Lett., 29, 6955 (1988).
• In combination with CuCl₂, catalyzes the photooxygenation of alcohols to aldehydes or ketones: J. Am. Chem. Soc., 107, 6116 (1985).