λ4-cerium(4+) ion bis(nitric acid) tetrakis(nitrooxidane) diamine

• ChemBase ID: 126470
• Molecular Formular: CeH8N8O18
• Molecular Mass: 548.22232
• Monoisotopic Mass: 547.90109346
• SMILES: [Ce+4].O=[N+]([O-])[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)O.[O-][N+](=O)O.[O-][N+](=O)[O-].N.N
• Canonical SMILES: [O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)O.[O-][N+](=O)O.N.N.[Ce+4]
• InChI: InChI=1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1
• InChIKey: WIBGOERAEYJBOT-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: λ^4-cerium(4+) ion bis(nitric acid) tetrakis(nitrooxidane) diamine; λ^4-cerium(4+) ion bis(nitric acid) diamine tetranitrate
• IUPAC Traditional name: λ^4-cerium(4+) ion bis(acid, nitric) diamine tetranitronate; λ^4-cerium(4+) ion bis(acid, nitric) diamine tetranitrate
• Synonyms: Ammonium cerium(IV) nitrate solution; Ceric ammonium nitrate (CAN); Ceric ammonium nitrate; Ceric ammonium nitrate; Ammonium cerium(IV) nitrate; 硝酸铈(IV)铵 溶液; 硝酸铈铵; 硝酸铈(IV)铵

Database IDs

• CAS Number: 16774-21-3
• EC Number: 240-827-6
• MDL Number: MFCD00151121
• PubChem SID: 24865042; 24853337; 24852897; 24892636; 24863843; 24853335; 162220804; 24853285; 24867008
• PubChem CID: 16211559
• Chemspider ID: 17339538
• Wikipedia Title: Ceric_ammonium_nitrate

CALCULATED PROPERTIES

• Acid pKa: -1.3999903
• H Acceptors: 3
• H Donor: 1
• LogD (pH = 5.5): -2.3479722
• LogD (pH = 7.4): -2.3479848
• Log P: 0.028413763
• Molar Refractivity: 10.473 cm^3
• Polarizability: 3.677472 Å^3
• Polar Surface Area: 66.05 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Solubility: 141 g/100 mL (25 °C); 227 g/100 mL (80 °C) in water
• Apperance: crystalline; orange-red crystals
• Melting Point: 107-108 °C
• Density: 1.10 g/mL at 20 °C

Safety Information

• European Hazard Symbols: Oxidising (O); Irritant (Xi)
• UN Number: 1477
• German water hazard class: 3
• Hazard Class: 5.1
• Packing Group: 2
• Risk Statements: 8-22-36/37/38
• Safety Statements: 17-26-36
• GHS Pictograms: GHS03; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H302-H315-H319-H335
• GHS Precautionary statements: P220-P261-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, Gloves
• RID/ADR: UN 1477 5.1/PG 2

Product Information

• Purity: ≥95.0%; ≥98% (titration); ≥98.0% (T); ≥98.5%; ≥98.5% (RT); ≥99.99% trace metals basis; 99.99%
• Concentration: 0.1 M Ce(NH4)2(NO3)6
• Grade: ACS reagent; JIS special grade; puriss. p.a.; purum p.a.; Reag. Ph. Eur.; SAJ first grade; semiconductor grade PURANAL™ (Honeywell 17732)
• Impurities: <100 ppm total metallic impurities; ≤0.05% insol. dil. H2SO4
• Cation Traces: Ca: ≤10 mg/kg; Ca: ≤50 mg/kg; Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: ≤0.005%; Fe: ≤50 mg/kg; K: ≤10 mg/kg; K: ≤100 mg/kg; Mg: ≤20 mg/kg; Mn: ≤5 mg/kg; Na: ≤10 mg/kg; Na: ≤100 mg/kg; Ni: ≤5 mg/kg; Ni: ≤50 mg/kg; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: chloride (Cl-): ≤0.01%; chloride (Cl-): ≤10 mg/kg; chloride (Cl-): ≤50 mg/kg; phosphate (PO43-): ≤0.02%; phosphate (PO43-): ≤200 mg/kg
• Shelf Life: (limited shelf life, expiry date on the label)
• Quality: volumetric
• Factor: 1.000 ±0.001
• Linear Formula: Ce(NH4)2(NO3)6

DETAILS

Sigma Aldrich - 40206

Legal Information
PURANAL is a trademark of Honeywell Specialty Chemicals Seelze GmbH

Sigma Aldrich - 431338

Features and Benefits
Meets ACS reagent specifications.
Packaging
50, 250 g in poly bottle
Application
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.1

Sigma Aldrich - 229547

Packaging
10, 50, 250 g in poly bottle
Application
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.1

Sigma Aldrich - 38187

Application
Reagent for the determination of arsenic. 1 mL of 0.1 M ammonium cerium nitrate is equivalent to 4.946 mg of As2O3.
General description
Visit our Titration Center to learn more.

Sigma Aldrich - C3654

包装
250 g in poly bottle

Sigma Aldrich - 22250

Other Notes
Versatile oxidizing agent1

Sigma Aldrich - 215473

Packaging
50, 250, 500 g in poly bottle
Application
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.1