trichlorobismuthane

• ChemBase ID: 126179
• Molecular Formular: BiCl3
• Molecular Mass: 315.3394
• Monoisotopic Mass: 313.88695604
• SMILES: Cl[Bi](Cl)Cl
• Canonical SMILES: Cl[Bi](Cl)Cl
• InChI: InChI=1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
• InChIKey: JHXKRIRFYBPWGE-UHFFFAOYSA-K

NAMES AND DATABASE IDS

Names

• IUPAC name: trichlorobismuthane
• IUPAC Traditional name: bismuth chloride
• Synonyms: Trichlorobismuth; Bismuth(III) chloride; Bismuth(III) chloride, anhydrous; Bismuth trichloride; Trichlorobismute; Trichlorobismuthine; Bismuth(III) chloride; Bismuth chloride; 氯化铋(III); 氯化铋(III),无水

Database IDs

• CAS Number: 7787-60-2
• EC Number: 232-123-2
• MDL Number: MFCD00003461
• Merck Index: 141262
• PubChem SID: 24853458; 24855360; 24890147; 24870650; 162220520; 24868263
• PubChem CID: 24591
• Chemspider ID: 22993
• Wikipedia Title: Bismuth_chloride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.0535
• LogD (pH = 7.4): 2.0535
• Log P: 2.0535
• Molar Refractivity: 18.4089 cm^3
• Polarizability: 15.121539 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: Decomposes to bismuth oxychloride in water; Soluble in HCl, HNO3, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl; soluble in methanol, diethyl ether, acetone
• Apperance: beads; hygroscopic white to yellow crystals; powder; Powder; solid
• Melting Point: 227°C; 230-232 °C(lit.); 230-232°C
• Boiling Point: 447 °C(lit.); 447°C; ca 430°C subl.
• Density: 4.75; 4.75 g/cm^3
• Heat Capacity: 0.333 J/(g K)
• Std enthalpy of formation: -1.202 kJ/g

Safety Information

• Storage Warning: Hygroscopic
• RTECS: EB2690000
• European Hazard Symbols: Corrosive (C); Irritant (Xi)
• UN Number: UN3260
• German water hazard class: 2
• Hazard Class: 8
• Packing Group: III
• Risk Statements: 34; 36/38
• Safety Statements: 26-36; 26-36/37/39-45; R
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS07
• GHS Signal Word: Warning
• NFPA704:
  

  0

  2

  0
• LD50: 3324 mg/kg, oral (rat)
• GHS Hazard statements: H314-H318; H315-H319
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A; P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves

Product Information

• Purity: ≥97.0% (KT); ≥98%; 99.9% (metals basis); 99.99% trace metals basis; 99.999% trace metals basis
• Grade: anhydrous; purum p.a.; reagent grade
• Particle Size: -10 mesh
• Impurities: ≤3% water
• Cation Traces: Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤100 mg/kg; Na: ≤200 mg/kg; Ni: ≤50 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: sulfate (SO42-): ≤500 mg/kg
• Empirical Formula (Hill Notation): BiCl3

DETAILS

Sigma Aldrich - 450723

Packaging
5, 25 g in ampule

Sigma Aldrich - 470279

Packaging
5, 25 g in ampule

Sigma Aldrich - 254142

Packaging
25 g in poly bottle

Sigma Aldrich - 224839

Packaging
25, 100, 500 g in poly bottle