dichloropalladium

• ChemBase ID: 111297
• Molecular Formular: Cl2Pd
• Molecular Mass: 177.326
• Monoisotopic Mass: 175.84119136
• SMILES: Cl[Pd]Cl
• Canonical SMILES: Cl[Pd]Cl
• InChI: InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
• InChIKey: PIBWKRNGBLPSSY-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: dichloropalladium
• IUPAC Traditional name: palladium chloride
• Synonyms: Palladium(II) chloride solution; Palladium II Chloride; Palladous Chloride; NCI-C60184; PALLADIUM CHLORIDE; Palladium(II) chloride; 氯化钯(II) 溶液; 氯化钯(II)

Database IDs

• CAS Number: 7647-10-1
• EC Number: 231-115-6; 231-596-2
• MDL Number: MFCD00003558
• PubChem SID: 162097070; 24848884; 24857119; 24874155; 24886928; 24852359; 24859361
• PubChem CID: 24290

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.269
• LogD (pH = 7.4): 1.269
• Log P: 1.269
• Molar Refractivity: 12.2726 cm^3
• Polarizability: 9.574385 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: powder
• Melting Point: 678-680 °C(lit.)
• Density: 1.06 g/mL at 25 °C; 4 g/mL at 25 °C(lit.)

Safety Information

• RTECS: RT3500000
• European Hazard Symbols: Corrosive (C); Toxic (T); Harmful (Xn)
• UN Number: 1789
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 3
• Risk Statements: 22-34-43; 25-43
• Safety Statements: 26-27/28-36/37-36/37/39-45; 36/37-45
• GHS Pictograms: GHS05; GHS06; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H317; H314-H317
• GHS Precautionary statements: P280-P301 + P310; P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• RID/ADR: UN 1789 8/PG 3

Product Information

• Purity: ≥99.0%; ≥99.9%; 59.0% Pd basis; 59-60% palladium (Pd) basis; 59-60% Pd basis; 60% Pd basis; 99%; 99.999%
• Concentration: 5 wt. % in 10 wt. % HCl
• Grade: JIS special grade; ReagentPlus®
• Compostion: Pd, 59-60%
• Linear Formula: PdCl2
• Empirical Formula (Hill Notation): Cl2Pd

DETAILS

MP Biomedicals - 05218554

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 323373

Packaging
1, 5 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 283606

Packaging
50 mL in glass bottle
Application
Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 520659

Application
This material is an efficient catalyst for the Mizoroki-Heck reaction2
Used as a catalyst together with Cu(II) for deamination of phenethylamines to phenyl substituted pyrroles. Together with PEG 300 promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids..
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
Packaging
1, 5, 25 g in glass bottle

Sigma Aldrich - 76050

Other Notes
Review2,3
Packaging
1, 5, 25 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 14814

Application
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes.
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 205885

Analysis Note
Used as a catalyst together with Cu(II) for deamination of phenethylamine to phenyl substituted pyrroles.2 Efficient Suzuki coupling of aryl chlorides with aryl boronic acids using catalytic PEG (300)-PdCl2.3
Packaging
1, 5, 25, 100, 150 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Sigma Aldrich - 24-0100

Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 14757

Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1