silver(1+) ion perchlorate

• ChemBase ID: 111275
• Molecular Formular: AgClO4
• Molecular Mass: 207.3188
• Monoisotopic Mass: 205.85360816
• SMILES: [Ag+].[O-][Cl](=O)(=O)=O
• Canonical SMILES: [O-][Cl](=O)(=O)=O.[Ag+]
• InChI: InChI=1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1
• InChIKey: YDHABVNRCBNRNZ-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: silver(1+) ion perchlorate
• IUPAC Traditional name: silver(1+) ion perchlorate; silver(1+) perchlorate ion
• Synonyms: Perchloric acid; silver(1+) salt; Silver perchlorate; Silver perchlorate; Silver perchlorate hydrate; SILVER PERCHLORATE, ANHYDROUS; Silver perchlorate, anhydrous; 高氯酸银; 高酸银水合物; 高氯酸银, 无水

Database IDs

• CAS Number: 331717-44-3; 7783-93-9
• EC Number: 231-131-3; 232-035-4
• MDL Number: MFCD00149128; MFCD00003400
• Merck Index: 148523
• PubChem SID: 162096592; 24885223
• PubChem CID: 24562
• Chemspider ID: 22968
• Wikipedia Title: Silver_perchlorate

CALCULATED PROPERTIES

• Acid pKa: -6.8919964
• H Acceptors: 4
• H Donor: 0
• LogD (pH = 5.5): -2.4740524
• LogD (pH = 7.4): -2.4740524
• Log P: -0.097653694
• Molar Refractivity: 11.9079 cm^3
• Polarizability: 5.355259 Å^3
• Polar Surface Area: 74.27 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: 5570 g/L in water; benzene: slightly soluble; pyridine: slightly soluble; Soluble in water and many organic solvents (benzene, toluene, pyridine)
• Apperance: Colorless hygroscopic crystals; Crystalline; solid
• Melting Point: 485°C dec.; 486 °C (decomp.); 486 °C(lit.)
• Density: 2.8 g/mL at 25 °C(lit.); 2.800; 2.806; 2.806 g/cm^3

Safety Information

• Storage Warning: Light Sensitive & Hygroscopic
• European Hazard Symbols: Corrosive (C); Nature polluting (N); Oxidising (O); Harmful (Xn)
• UN Number: 1481; UN1481
• German water hazard class: 3
• Hazard Class: 5.1
• Packing Group: 2; II
• Risk Statements: 8-34; 8-34-50; R:8-22; R8 R34 R50
• Safety Statements: 17-26-27-36/37/39; 17-26-36/37/39-45-61; S:17-36/37/39; S15 S17 S26 S36/37/39 S45
• TSCA Listed: 是
• GHS Pictograms: GHS03; GHS05; GHS09
• GHS Signal Word: Danger
• NFPA704:
  

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• GHS Hazard statements: H272-H314; H272-H314-H318-H400
• GHS Precautionary statements: P220-P280-P305 + P351 + P338-P310; P221-P280-P273-P303+P361+P353-P305+P351+P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1481 5.1/PG 2

Product Information

• Purity: 97%; 98%; 99.9%
• Grade: anhydrous
• Compostion: Ag, >50.5%
• Linear Formula: AgClO4

DETAILS

Sigma Aldrich - 674583

Packaging
5, 25 g in poly bottle

Sigma Aldrich - 449237

Packaging
5 g in poly bottle
Application
Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.1

REFERENCES

• Silver salt soluble in water and organic solvents. Used as a mild dehydrating agent for secondary and tertiary alcohols to alkenes: Chem. Lett., 287 (1972); Synth. Commun., 8, 3 (1978). Catalyst for a variety of rearrangement processes of strained systems: Synthesis, 347 (1975); Chem. Rev., 76, 461 (1976). In the presence of various Lewis acids, can be used to promote glycosidation reactions: Angew. Chem. Int . Ed., 21, 155 (1982); Chem. Rev., 93, 1503 (1993).