lanthanum(3+) ion tris(nitrooxidane) hexahydrate

• ChemBase ID: 108941
• Molecular Formular: H12LaN3O15
• Molecular Mass: 433.01188
• Monoisotopic Mass: 432.9331947
• SMILES: O.O.O.O.O.O.[La+3].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-]
• Canonical SMILES: [O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].O.O.O.O.O.O.[La+3]
• InChI: InChI=1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1
• InChIKey: GJKFIJKSBFYMQK-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: lanthanum(3+) ion tris(nitrooxidane) hexahydrate; lanthanum(3+) ion hexahydrate trinitrate
• IUPAC Traditional name: lanthanum(3+) hexahydrate trinitronate; lanthanum(3+) ion hexahydrate trinitrate
• Synonyms: LANTHANUM NITRATE; Nitric acid, lanthanum (III) salt, hexahydrate; Lanthanum(III) nitrate hexahydrate; Lanthanum(III) nitrate hydrate; Lanthanum(III) nitrate hexahydrate, REacton®; 硝酸镧(III) 六水合物; 硝酸镧(III) 五水合物; 硝酸镧(III) 六水合物, REacton®

Database IDs

• CAS Number: 100587-94-8; 10277-43-7
• EC Number: 233-238-0
• MDL Number: MFCD00011067; MFCD00149751
• Merck Index: 145363
• PubChem SID: 24860011; 24882149; 162096123; 24852179
• PubChem CID: 16211478

CALCULATED PROPERTIES

• Acid pKa: -1.3999903
• H Acceptors: 3
• H Donor: 0
• LogD (pH = 5.5): 0.8368004
• LogD (pH = 7.4): 0.8368004
• Log P: 0.8368004
• Molar Refractivity: 8.3471 cm^3
• Polarizability: 3.4222581 Å^3
• Polar Surface Area: 66.2 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: Soluble in water and alcohol
• Apperance: crystalline; Crystalline; Crystalline Aggregates; solid
• Melting Point: 40°C; 65-68 °C

Safety Information

• RTECS: OE5075000; OE5250000
• European Hazard Symbols: Oxidising (O); Irritant (Xi)
• UN Number: 1477; UN1477
• German water hazard class: 3
• Hazard Class: 5.1
• Packing Group: 2; III
• Risk Statements: 8-36/37/38; R:9-18
• Safety Statements: 17-26-36; 17-26-37; 17-26-37-60; S:13-16-27
• TSCA Listed: 是
• GHS Pictograms: GHS03; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H315-H319-H335; H272-H315-H319-H335-H303
• GHS Precautionary statements: P220-P261-P305 + P351 + P338; P221-P210-P305+P351+P338-P302+P352-P405-P501A
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1477 5.1/PG 2

Product Information

• Purity: ≥99.0% (titration); 99%, water ca 22-25%; 99.9% (REO); 99.99% (REO); 99.99% trace metals basis; 99.999% trace metals basis
• Grade: puriss. p.a.
• Cation Traces: Ca: ≤50 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤10 mg/kg; K: ≤10 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Na: ≤10 mg/kg; Ni: ≤5 mg/kg; Pb: ≤10 mg/kg; Zn: ≤5 mg/kg
• Antion Traces: chloride (Cl-): ≤50 mg/kg; sulfate (SO42-): ≤50 mg/kg
• Linear Formula: La(NO3)3 · 6H2O

DETAILS

MP Biomedicals - 05209319

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 331937

Packaging
5, 100, 500 g in glass bottle
Application
Starting material for the electrochemical synthesis of a LaMnO3 thin film coating on stainless steel substrates.1 A novel solvothermal process for formation of doped lanthanide oxysulfide, La2O2S, was developed in order to advance possible applications of this material in phosphors, fluorescent display tubes or heat transfer measurement.2

Sigma Aldrich - 203548

Packaging
25, 100, 500 g in glass bottle
Application
Starting material for the electrochemical synthesis of a LaMnO3 thin film coating on stainless steel substrates.1 A novel solvothermal process for formation of doped lanthanide oxysulfide, La2O2S, was developed in order to advance possible applications of this material in phosphors, fluorescent display tubes or heat transfer measurement.2

REFERENCES

• Mild and efficient catalyst for t-butoxycarbonylation of amines with Di-tert-butyl dicarbonate, A14708: Tetrahedron Lett., 47, 8039 (2006).