lithium(1+) ion trihydrate perchlorate

• ChemBase ID: 108923
• Molecular Formular: ClH6LiO7
• Molecular Mass: 160.43744
• Monoisotopic Mass: 159.99620976
• SMILES: [Li+].O.O.O.[O-][Cl](=O)(=O)=O
• Canonical SMILES: [O-][Cl](=O)(=O)=O.[Li+].O.O.O
• InChI: InChI=1S/ClHO4.Li.3H2O/c2-1(3,4)5;;;;/h(H,2,3,4,5);;3*1H2/q;+1;;;/p-1
• InChIKey: JAWYRNYHJJDXHX-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion trihydrate perchlorate
• IUPAC Traditional name: LithoTab trihydrate perchlorate ion; lithium(1+) ion trihydrate perchlorate
• Synonyms: LITHIUM PERCHLORATE TRIHYDRATE; Lithium perchlorate trihydrate; Lithium perchlorate trihydrate, Reagent Grade; 高氯酸锂 三水合物; 三水合高氯酸锂, 试剂级

Database IDs

• CAS Number: 13453-78-6
• EC Number: 232-237-2
• MDL Number: MFCD00149765
• Merck Index: 145539
• PubChem SID: 24852322; 162094473
• PubChem CID: 23708903

CALCULATED PROPERTIES

• Acid pKa: -6.8919964
• H Acceptors: 4
• H Donor: 0
• LogD (pH = 5.5): -2.4740524
• LogD (pH = 7.4): -2.4740524
• Log P: -0.097653694
• Molar Refractivity: 11.9079 cm^3
• Polarizability: 5.355259 Å^3
• Polar Surface Area: 74.27 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: Crystalline
• Density: 1.84; 1.841 g/mL at 25 °C(lit.)

Safety Information

• RTECS: SC8750000
• European Hazard Symbols: Oxidising (O); Irritant (Xi)
• UN Number: 1481; UN1481
• German water hazard class: 1
• Hazard Class: 5.1
• Packing Group: 2; II
• Risk Statements: 8-36/37/38
• Safety Statements: 17-26-27-36/37/39; 17-26-37-60
• TSCA Listed: 是
• GHS Pictograms: GHS03; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H315-H319-H335
• GHS Precautionary statements: P220-P261-P305 + P351 + P338; P221-P210-P305+P351+P338-P302+P352-P405-P501A
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1481 5.1/PG 2

Product Information

• Purity: 99.8%
• Linear Formula: LiClO4 · 3H2O

DETAILS

MP Biomedicals - 05209241

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 205303

Packaging
1 kg in glass bottle
50, 250 g in glass bottle
Application
When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.1