dodecanoyl dodecaneperoxoate

• ChemBase ID: 108088
• Molecular Formular: C24H46O4
• Molecular Mass: 398.61964
• Monoisotopic Mass: 398.33960995
• SMILES: CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC
• Canonical SMILES: CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC
• InChI: InChI=1S/C24H46O4/c1-3-5-7-9-11-13-15-17-19-21-23(25)27-28-24(26)22-20-18-16-14-12-10-8-6-4-2/h3-22H2,1-2H3
• InChIKey: YIVJZNGAASQVEM-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: dodecanoyl dodecaneperoxoate
• IUPAC Traditional name: peroxide, bis(1-oxododecyl)
• Synonyms: Dilauroyl peroxide; Dodecanoyl peroxide; Lauroyl peroxide; Luperox® LP, Lauroyl peroxide; Lauroyl peroxide; DILAUROYL PEROXIDE; Dodecanoic peroxyanhydride; 过氧化十二烷酰; 过氧化双月桂酰; 过氧化月桂酰; Luperox® LP, 过氧化月桂酰; 过氧化月桂酰

Database IDs

• CAS Number: 105-74-8
• EC Number: 203-326-3
• MDL Number: MFCD00008964
• Beilstein Number: 1804936
• PubChem SID: 162093896; 24874842; 24857486
• PubChem CID: 7773

CALCULATED PROPERTIES

• H Acceptors: 2
• H Donor: 0
• LogD (pH = 5.5): 9.241891
• LogD (pH = 7.4): 9.241891
• Log P: 9.241891
• Molar Refractivity: 115.504 cm^3
• Polarizability: 46.461414 Å^3
• Polar Surface Area: 52.6 Å^2
• Rotatable Bonds: 23
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Melting Point: 53-57 °C; 53-57 °C(lit.); 53-57°C
• Density: 0.910
• Vapor Density: 13.7 (vs air)

Safety Information

• RTECS: OF2625000
• European Hazard Symbols: Oxidising (O)
• UN Number: 3106; UN3106
• German water hazard class: 1
• Hazard Class: 5.2
• Packing Group: II
• Risk Statements: 7; R:9-18
• Safety Statements: 3/7-14-36/37/39; S:13-16-27
• TSCA Listed: 是
• GHS Pictograms: GHS02
• GHS Signal Word: Danger
• GHS Hazard statements: H242
• GHS Precautionary statements: P210-P220-P280-P410-P420-P501A; P220-P280-P410-P410 + P412-P420; P220-P280-P410-P411 + P235-P420
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3106 5.2
• Storage Temperature: 2-8°C

Product Information

• Purity: ≥95.0% (RT); 95+%; 97%
• Grade: purum
• Linear Formula: [CH3(CH2)10CO]2O2

DETAILS

MP Biomedicals - 05206036

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 290785

Packaging
5, 100, 500 g in poly bottle
Legal Information
Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Sigma Aldrich - 61740

Other Notes
Sales restrictions may apply

REFERENCES

• Free-radical initiator. Xanthates undergo hydrodesulfurization with the reagent in refluxing isopropanol: Tetrahedron Lett., 37, 5877 (1996). The reaction has been extended to the cyclization of 3-aroylpropyl xanthates to tetralones: Tetrahedron Lett., 38, 1759 (1997); 1,2,3,4-tetrahydroisoquinolin-1-ones can be prepared similarly: Tetrahedron Lett., 39, 7295 (1998).