(iodomethyl)trimethylsilane

• ChemBase ID: 107510
• Molecular Formular: C4H11ISi
• Molecular Mass: 214.12011
• Monoisotopic Mass: 213.96747488
• SMILES: C[Si](C)(C)CI
• Canonical SMILES: IC[Si](C)(C)C
• InChI: InChI=1S/C4H11ISi/c1-6(2,3)4-5/h4H2,1-3H3
• InChIKey: VZNYXGQMDSRJAL-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: (iodomethyl)trimethylsilane
• IUPAC Traditional name: (iodomethyl)trimethylsilane
• Synonyms: (Trimethylsilyl)methyl iodide; (Iodomethyl)trimethylsilane; (IODOMETHYL)TRIMETHYLSILANE; (三甲基硅)甲基碘; 碘甲基三甲基硅烷

Database IDs

• CAS Number: 4206-67-1
• EC Number: 224-123-6
• MDL Number: MFCD00001077
• Beilstein Number: 1731485
• PubChem SID: 24880966; 162093487
• PubChem CID: 77877

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.7461
• LogD (pH = 7.4): 3.7461
• Log P: 3.7461
• Molar Refractivity: 34.9158 cm^3
• Polarizability: 16.085732 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 1
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 139-141 °C(lit.)
• Flash Point: 29 °C; 84.2 °F
• Density: 1.443 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.491; n20/D 1.491(lit.)

Safety Information

• European Hazard Symbols: Irritant (Xi)
• UN Number: 2924
• German water hazard class: 3
• Hazard Class: 3
• Packing Group: 3
• Risk Statements: 10-36/37/38; R:36/37/38
• Safety Statements: 26-36; S:20-25-26-37/39
• GHS Pictograms: GHS02; GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2924 3/PG 3

Product Information

• Purity: ≥99.0% (GC); 99%
• Contains: copper as stabilizer
• Linear Formula: (CH3)3SiCH2I

DETAILS

MP Biomedicals - 05204024

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 57903

Other Notes
Starting material for the preparation of 2-(trimethylsilyl)ethyl-triphenylphosphonium iodide used for the synthesis of allyl silanes1,2; Used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions3
Packaging
5, 25 mL in glass bottle