indium(3+) ion trichloride

• ChemBase ID: 107321
• Molecular Formular: Cl3In
• Molecular Mass: 221.177
• Monoisotopic Mass: 219.81043604
• SMILES: [Cl-].[Cl-].[Cl-].[In+3]
• Canonical SMILES: [Cl-].[Cl-].[Cl-].[In+3]
• InChI: InChI=1S/3ClH.In/h3*1H;/q;;;+3/p-3
• InChIKey: PSCMQHVBLHHWTO-UHFFFAOYSA-K

NAMES AND DATABASE IDS

Names

• IUPAC name: indium(3+) ion trichloride
• IUPAC Traditional name: indium(3+) trichloride; indium(3+) ion trichloride
• Synonyms: INDIUM CARBONATE; Indium(III) chloride, ultra dry; Indium(III) chloride, anhydrous; 氯化铟(III), 超干; 氯化铟(III), 无水; 氯化铟, 无水

Database IDs

• CAS Number: 13465-10-6; 10025-82-8
• EC Number: 236-693-3; 233-043-0
• MDL Number: MFCD00011058
• Merck Index: 144958
• PubChem SID: 162094854
• PubChem CID: 159675

CALCULATED PROPERTIES

• Acid pKa: -7.0
• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• Molar Refractivity: 5.6156 cm^3
• Polarizability: 2.1090326 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: Soluble in water
• Apperance: Crystalline; Powder, Ampouled under argon
• Melting Point: 586°C
• Boiling Point: 800°C
• Density: 3.460

Safety Information

• Storage Warning: Hygroscopic
• RTECS: NL1400000
• European Hazard Symbols: Corrosive (C); X
• UN Number: UN3260
• Hazard Class: 8
• Packing Group: II
• Risk Statements: 22-34
• Safety Statements: 20-26-36/37/39-45-60
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS06
• GHS Hazard statements: H301-H314-H318
• GHS Precautionary statements: P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A

Product Information

• Purity: 98+%; 99.99% (metals basis); 99.999% (metals basis)

DETAILS

MP Biomedicals - 05203323

MP Biomedicals Rare Chemical collection

REFERENCES

• Promotes efficient azidolysis of ɑ?-epoxy carboxyl derivatives in water at pH 4, with results superior to Yb(OTf)₃ or Sc(OTf)₃: J. Org. Chem., 66, 3554 (2001).
• Indium enolates are readily formed by transmetallation of Li enolates. These undergo Reformatsky-type reactions with aldehydes to give ?-hydroxy esters. ɑ-Bromo enolates give Darzens-type ɑ?-epoxy carbonyl compounds: J. Chem. Soc., Perkin 1, 825 (2000).
• The combination with NaBH₄ has been reported to be an effective radical reducing system, replacing the environmentally unfavorable TBTH (Tri-n-butyltin hydride, A13298), e.g. in dehalogenation and cyclization reactions: J. Am. Chem. Soc., 124, 906 (2002).
• In combination with Triethylsilane, A10320 and a radical initiator, generates a radical reagent, analogous to Tri-n-butyltin hydride, A13298: Org. Lett., 6, 4981 (2004).
• For a brief feature on InCl₃, see: Synlett, 531 (2002). For reviews of the use of In compounds in organic synthesis, see: Eur. J. Org. Chem., 2347 (2000); J. Chem. Soc., Perkin 1, 3015 (2000).
• Mild, water tolerant Lewis acid catalyst, e.g. in allylation reactions of sensitive aldehydes with allyltributyltin: J. Org Chem., 61, 105 (1996). The allylstannane can also be generated in situ from the allyl halidein water: Tetrahedron Asym., 7, 1535 (1996). Catalyzes the Mukaiyama aldol reaction, under either solvent-free conditions: Tetrahedron Lett., 39, 1579 (1998), or in water: Chem. Commun., 1819 (1996); 861 (1998); Tetrahedron Lett., 38, 3465 (1997).For Diels-Alder reactions in water, see: Chem. Commun., 2315 (1996).
• In combination with a dithiol, catalyzes the efficient transthioacetalization of acetals to dithioacetals: Synlett, 727 (2002).
• Aldoximes can be dehydrated to nitriles; ketoximes undergo the Beckmann rearrangement to amides: Chem. Commun., 1196 (2000).
• Catalyst for conjugate addition of indoles to electron-deficient alkenes: Synthesis, 2165 (2001):