lithium(1+) ion methanolate

• ChemBase ID: 106774
• Molecular Formular: CH3LiO
• Molecular Mass: 37.97492
• Monoisotopic Mass: 38.03439427
• SMILES: [Li+].C[O-]
• Canonical SMILES: [O-]C.[Li+]
• InChI: InChI=1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
• InChIKey: JILPJDVXYVTZDQ-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion methanolate
• IUPAC Traditional name: LithoTab methoxide; lithium(1+) ion methoxide
• Synonyms: LITHIUM METHOXIDE; Lithium methoxide solution; Lithium methylate; Lithium methoxide; 甲醇锂 溶液; 甲氧基锂; 甲醇锂; 甲氧基锂

Database IDs

• CAS Number: 865-34-9
• EC Number: 212-737-7
• MDL Number: MFCD00036357
• Beilstein Number: 3552389
• PubChem SID: 24865594; 24882243; 24861245; 162093464
• PubChem CID: 4177230

CALCULATED PROPERTIES

• Acid pKa: 15.775593
• H Acceptors: 1
• H Donor: 0
• LogD (pH = 5.5): -0.51857704
• LogD (pH = 7.4): -0.5185771
• Log P: -0.51857704
• Molar Refractivity: 18.8116 cm^3
• Polarizability: 2.9253356 Å^3
• Polar Surface Area: 23.06 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: powder; Powder
• Melting Point: >500°C dec.
• Boiling Point: 64.6 °C
• Flash Point: 11 °C; 12 °C; 20 °C; 51.8 °F; 53.6 °F; 68 °F
• Density: 0.817 g/mL at 20 °C; 0.817 g/mL at 25 °C; 0.85 g/mL at 20 °C

Safety Information

• Storage Warning: Air & Moisture Sensitive
• European Hazard Symbols: Corrosive (C); Flammable (F); Toxic (T)
• UN Number: 3206; 3274; UN3206
• German water hazard class: 3
• Hazard Class: 3; 4.2
• Packing Group: 2; II
• Risk Statements: 11-14-23/24/25-34-39/23/24/25; 11-14-23/24/25-36/38-39/23/24/25; 11-14-34; R:14/15-34
• Safety Statements: 16-26-36/37/39-45; 16-26-36/37-45; 8-16-26-43-45; S:8-45
• TSCA Listed: 是
• GHS Pictograms: GHS02; GHS05; GHS06; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H251-H301-H311-H314-H331-H370; H251-H314
• GHS Precautionary statements: P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338; P235 + P410-P280-P305 + P351 + P338-P310; P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US); Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 3206 4.2/PG 2; UN 3274 3/PG 2
• Supplemental Hazard Statements: Reacts violently with water.

Product Information

• Purity: ≥90% (T); 98%; 98+%
• Concentration: ~10% in methanol (T, ~2.2 M); ~4.6% in methanol (~1 M); 1.0 M in methanol
• Grade: purum; technical
• Impurities: ~2% Li2CO3 and LiOH
• Linear Formula: CH3OLi

DETAILS

MP Biomedicals - 05201382

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 408794

Packaging
100, 800 mL in Sure/Seal™
Application
Employed in sol-gel synthesis of lithium borophosphates.1

Sigma Aldrich - 344370

Packaging
25, 100 g in glass bottle
Application
Employed in sol-gel synthesis of lithium borophosphates.1

Sigma Aldrich - 62562

Packaging
100 mL in Sure/Seal™