NAMES AND DATABASE IDS
NAMES AND DATABASE IDS
Names Database IDs
IUPAC name
|
λ?-cerium(4+) ion diammonium hexakis(nitrooxidane)
|
λ4-cerium(4+) ion diammonium hexanitrate
|
|
|
IUPAC Traditional name
|
λ4-cerium(4+) ion diammonium hexanitronate
|
λ4-cerium(4+) ion diammonium hexanitrate
|
|
|
Synonyms
|
Cerium(IV) ammonium nitrate, ACS
|
Ammonium cerium IV Nitrate
|
CERIC AMMONIUM NITRATE ACS REAGENT GRADE
|
Ammonium cerium(IV) nitrate
|
CAN
|
Cerium(IV) ammonium nitrate
|
Cerium(IV) ammonium nitrate, REacton®
|
硝酸铈(Ⅳ)铵, ACS
|
硝酸铈(Ⅳ)铵
|
硝酸铈(Ⅳ)铵, REacton®
|
|
|
CAS Number
|
|
EC Number
|
|
MDL Number
|
|
Merck Index
|
|
PubChem SID
|
|
PubChem CID
|
|
DATA SOURCES
DATA SOURCES
All Sources Commercial Sources Non-commercial Sources
CALCULATED PROPERTIES
CALCULATED PROPERTIES
JChem
Acid pKa
|
-1.3999903
|
H Acceptors
|
3
|
H Donor
|
0
|
LogD (pH = 5.5)
|
0.8368004
|
LogD (pH = 7.4)
|
0.8368004
|
Log P
|
0.8368004
|
Molar Refractivity
|
8.3471 cm3
|
Polarizability
|
3.4222581 Å3
|
Polar Surface Area
|
66.2 Å2
|
Rotatable Bonds
|
0
|
Lipinski's Rule of Five
|
false
|
DETAILS
DETAILS
MP Biomedicals
REFERENCES
REFERENCES
From Suppliers
Google Scholar
PubMed
Google Books
- • Catalyst for mild, selective opening of epoxides: Tetrahedron, 47, 9861 (1991).
- • The direct conversion of aldehydes to nitriles in aqueous NH3, under extremely mild conditions, is mediated by CAN: Synlett, 262 (2003).
- • Versatile oxidizing agent. For reviews, see: Chem. Rev., 92, 29 (1992); J. Prakt. Chem./ Chem. Ztg., 336, 470 (1994); Synlett, 834 (1999); 3014 (2005); Acc. Chem. Res., 37, 21 (2004). Examples of oxidations with CAN:
- • For formation of dithioacetals, see 1,2-Ethanedithiol, L12865. For cleavage of dithioacetals, see 1,3-Dithiane, A10505.
- • Selective conversion of alcohols to aldehydes: J. Chem. Soc., 5777 (1965); J. Org. Chem., 32, 2349, 3865 (1967). Oxidation of benzylic methyl groups to aldehydes or acetates: J. Org. Chem., 31, 2033 (1966); 45, 3906 (1980). For selective oxidation of 2-methylpyrroles to the aldehydes, see: Tetrahedron Lett., 36, 4345 (1995). Phenols to quinones: Synthesis, 347 (1973); Liebigs Ann. Chem., 1655, 1669 (1986). Cleavage of vic-diols to ketones and ɑ-hydroxy ketones to acids: J. Org. Chem., 34, 869 (1969); Synthesis, 560 (1972). Conversion of ɑ-diketones and a-keto esters to carboxylic acids: J. Org. Chem., 71, 4516 (2006). Oxidative bisdecarboxylation of malonic acid derivatives: Tetrahedron Lett., 29, 769 (1988). Regeneration of carbonyl compounds from oximes or semicarbazones: Can. J. Chem., 47, 145 (1969); Synthesis, 347 (1973). Catalytic deprotection of Boc protected alcohols, amines and thiols: Tetrahedron Lett., 37, 2035 (1996). Debenzylation of N-benzyl tertiary amines: J. Chem. Soc., Perkin 1, 3765 (2000). Decomplexation of transition metal π-complexes: Org. Synth. Coll., 8, 460 (1993). Oxidative addition of olefins to the ɑ-position of ketones: Tetrahedron Lett., 28, 5357 (1987); Synth. Commun., 18, 1841 (1988).
- Searching...Please wait...
PATENTS
PATENTS
PubChem Patent
Google Patent