tetrabutylazanium periodate

• ChemBase ID: 104677
• Molecular Formular: C16H36INO4
• Molecular Mass: 433.36581
• Monoisotopic Mass: 433.16890664
• SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-][I](=O)(=O)=O
• Canonical SMILES: [O-][I](=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: InChI=1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChIKey: PYVXLMQALOZKES-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: tetrabutylazanium periodate
• IUPAC Traditional name: tetrabutylammonium ion IO4; tetrabutylammonium periodate
• Synonyms: TETRABUTYLAMMONIUM PERIODATE; Tetrabutylammonium (meta)periodate; 四丁基高碘酸铵

Database IDs

• CAS Number: 65201-77-6
• EC Number: 265-614-5
• MDL Number: MFCD00011852
• Beilstein Number: 4621593
• PubChem SID: 24888808; 24854846; 162091913
• PubChem CID: 2724292

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.3234289
• LogD (pH = 7.4): 1.3234289
• Log P: 1.3234289
• Molar Refractivity: 91.3961 cm^3
• Polarizability: 31.734425 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 12
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: solid
• Melting Point: 175 °C (dec.)(lit.); 175°C; 184-185 °C

Safety Information

• Storage Condition: Room Temperature (15-30°C)
• European Hazard Symbols: Oxidising (O); Irritant (Xi)
• UN Number: 1479
• German water hazard class: 3
• Hazard Class: 5.1
• Packing Group: 2; II
• Australian Hazchem: 1Y
• Risk Statements: 8-36/37/38; R:9-18
• Safety Statements: 17-26-36; S:13-16-27
• EU Classification: O2
• EU Hazard Identification Number: 5.1B
• Emergency Response Guidebook(ERG) Number: 140
• GHS Pictograms: GHS03; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H315-H319-H335
• GHS Precautionary statements: P220-P261-P305 + P351 + P338
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1479 5.1/PG 2

Product Information

• Purity: ≥97.0% (calc. based on dry substance, T)
• Grade: purum
• Contains: ~10% water as stabilizer
• Quality: moistened with water
• Linear Formula: (CH3CH2CH2CH2)4N(IO4)

DETAILS

Sigma Aldrich - 247057

Packaging
25 g in glass bottle

Sigma Aldrich - 86889

Other Notes
Versatile reagent for oxidation in organic solvents1,2; Oxidation of 1,2-diols and olefins3; Oxidation of sulfides to sulfoxides4