lithium(1+) ion iodide

• ChemBase ID: 104256
• Molecular Formular: ILi
• Molecular Mass: 133.84547
• Monoisotopic Mass: 133.92047755
• SMILES: [Li+].[I-]
• Canonical SMILES: [Li+].[I-]
• InChI: InChI=1S/HI.Li/h1H;/q;+1/p-1
• InChIKey: HSZCZNFXUDYRKD-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion iodide
• IUPAC Traditional name: lithium(1+) ion iodide; LithoTab iodide
• Synonyms: Lithium iodide; Lithium iodide, ultra dry; LITHIUM IODIDE; Lithium iodide, anhydrous; 碘化锂; 碘化锂,超干; 碘化锂, 无水; 碘化锂, 超干; 碘化锂,无水

Database IDs

• CAS Number: 10377-51-2
• EC Number: 233-822-5
• MDL Number: MFCD00011092
• Merck Index: 145535
• PubChem SID: 24868594; 162092470; 24867537; 24873993; 24853051
• PubChem CID: 66321
• Chemspider ID: 59699
• Wikipedia Title: Lithium_iodide

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.0
• LogD (pH = 7.4): 0.0
• Log P: 0.0
• Molar Refractivity: 0.0 cm^3
• Polarizability: 1.7969184 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true
• Acid pKa: 3.09

PROPERTIES

Physical Property

• Solubility: 151 g/100 mL (25 °C) ; 433 g/100 mL (100 °C) in water; 343 g/100 mL (20 °C) in methanol; 42.6 g/100 mL (18 °C) in acetone; Soluble in water, alcohol, acetone and methanol. Very soluble in NH4OH
• Apperance: -10 Mesh Beads, Ampouled under argon; beads; crystalline powder; Crystalline/Powder, Ampouled under argon; Lumps/powder, Ampouled under argon; Powder, Ampouled under argon; White crystalline solid
• Melting Point: 446 °C(lit.); 449°C; 449°C; 469 °C
• Boiling Point: 1170°C; 1170-1190°C; 1171 °C
• Flash Point: Non-flammable
• Density: 3.49 g/mL at 25 °C(lit.); 4.076; 4.076 g/cm^3 (anhydrous) ; 3.494 g/cm^3 (trihydrate); 4.08 g/cc
• Refractive Index: 1.955
• Heat Capacity: 0.381 J/g K
• Std enthalpy of formation: -2.02 kJ/g

Safety Information

• Storage Condition: Room Temperature (15-30°C), Desiccate, Protect from light
• Storage Warning: Light Sensitive & Hygroscopic
• European Hazard Symbols: Irritant (Xi); Harmful (Xn)
• German water hazard class: 1; 3
• Risk Statements: 36/37/38; 36/38; R:22
• Safety Statements: 26; 26-37; S:46
• TSCA Listed: 是
• EU Index: Not listed
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319; H315-H319-H335
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A; P280-P305+P351+P338-P302+P352-P321-P362-P332+P313; P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves

Product Information

• Purity: ≥98.0% (AT); 98+%; 99%; 99% (metals basis); 99.9% trace metals basis; 99.95% (metals basis); 99.99% trace metals basis; 99.999% (metals basis); 99.999% trace metals basis
• Grade: anhydrous; purum
• Particle Size: -10 mesh
• Linear Formula: LiI

DETAILS

MP Biomedicals - 02155259

Produces a hazy solution at 50% (w/v) in H2O.

Sigma Aldrich - 450952

Application
Controls regioselectivity in palladium catalyzed allylic alkylation reactions.1
Packaging
5, 25 g in ampule

Sigma Aldrich - 218219

Application
Controls regioselectivity in palladium-catalyzed allylic alkylation reactions.1
Packaging
10, 50, 250, 6×250 g in glass bottle

Sigma Aldrich - 439746

Packaging
5, 25 g in ampule
Application
Controls regioselectivity in palladium catalyzed allylic alkylation reactions.1

Sigma Aldrich - 518018

Packaging
10, 50 g in glass bottle
Protocols & Applications
Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors

REFERENCES

• Can be used in refluxing pyridine or collidine for selective cleavage of methyl esters: Rocz. Chem., 30, 323 (1956); Helv. Chim. Acta, 43, 113 (1960). For review and comparison with other methods, see: Org. React., 24, 187 (1976).
• Also cleaves aralkyl ethers in collidine: Chem. Commun., 616 (1969); J. Am. Chem. Soc., 103, 4247 (1981).
• For rearrangement of oxaspiropentane to cyclobutanone with LiI, see: Org. Synth. Coll., 6, 320 (1988).