hydrazine; sulfuric acid

• ChemBase ID: 102976
• Molecular Formular: H6N2O4S
• Molecular Mass: 130.12364
• Monoisotopic Mass: 130.00482768
• SMILES: NN.OS(=O)(=O)O
• Canonical SMILES: OS(=O)(=O)O.NN
• InChI: InChI=1S/H4N2.H2O4S/c1-2;1-5(2,3)4/h1-2H2;(H2,1,2,3,4)
• InChIKey: ZGCHATBSUIJLRL-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: hydrazine; sulfuric acid
• IUPAC Traditional name: diamine; sulfuric acid; hydrazine; sulfuric acid
• Synonyms: Hydrazine Monosulfate; HYDRAZINE SULFATE; Hydrazine sulfate; Hydrazine sulfate, ACS; Hydrazine sulfate salt; Hydrazinium sulfate; Hydrazine sulfate salt; Hydrazine sulphate; 硫酸肼; 硫酸肼, ACS; Hydrazinium sulfate; 肼 硫酸盐

Database IDs

• CAS Number: 10034-93-2
• EC Number: 233-110-4; 204-563-5
• MDL Number: MFCD00044873
• Beilstein Number: 8778859
• Merck Index: 144772
• PubChem SID: 162089608; 24878375; 24869089; 24852935
• PubChem CID: 24842
• Chemspider ID: 23225
• Unique Ingredient Identifier: 1N369SAT01
• Wikipedia Title: Hydrazine_sulfate

CALCULATED PROPERTIES

• Acid pKa: -3.034349
• H Acceptors: 4
• H Donor: 2
• LogD (pH = 5.5): -5.569452
• LogD (pH = 7.4): -5.594027
• Log P: -0.841552
• Molar Refractivity: 13.7708 cm^3
• Polarizability: 6.279968 Å^3
• Polar Surface Area: 74.6 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: 30 g/L (20°C) in water
• Apperance: Crystalline
• Melting Point: 254 °C(lit.); 254°C; 254°C; ca 255°C dec.
• Density: 1.370; 1.370 g/ml

Safety Information

• Storage Condition: Room Temperature (15-30°C)
• RTECS: MV9625000; MW2625000
• European Hazard Symbols: Corrosive (C); Nature polluting (N); Toxic (T); Harmful (Xn)
• UN Number: 1759; 2923; 3077; UN3288
• German water hazard class: 3
• Hazard Class: 6.1; 8; 9
• Packing Group: 3; II; III
• Australian Hazchem: 2X
• Risk Statements: 45-22-50/53; 45-23/24/25-43-50/53; R:22-34-45
• Safety Statements: 53-45-60-61; S:27/28-29-36/37/39-45-53
• EU Classification: C10
• EU Hazard Identification Number: 8B
• Emergency Response Guidebook(ERG) Number: 154
• TSCA Listed: 是
• EU Index: 007-008-00-3
• GHS Pictograms: GHS06; GHS07; GHS08; GHS09
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H311-H317-H331-H350-H410; H301-H311-H331-H317-H350-H400-H410; H302-H350-H410
• GHS Precautionary statements: P201-P261-P273-P280-P301 + P310-P311; P201-P273-P308 + P313-P501; P261-P301+P310-P361-P302+P352-P405-P501A
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges; dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 2923 8/PG 3; UN 3077 9/PG 3

Product Information

• Purity: ≥97.0%; ≥98.0% (RT); ≥99% (iodometric); ≥99.0%; 97%; 99.0% min; 99.999% trace metals basis; 99+%
• Grade: ACS reagent; JIS special grade; puriss. p.a.; purum p.a.; SAJ first grade
• Ignition Residue: ≤0.05%; ≤0.05% (as SO4)
• Impurities: ≤0.0005% heavy metals (as Pb); ≤0.005% insolubles
• Cation Traces: Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: ≤0.001%; Fe: ≤10 mg/kg; Fe: ≤5 mg/kg; Fe: ≤50 mg/kg; heavy metals (as Pb): ≤0.002%; K: ≤100 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Na: ≤100 mg/kg; Na: ≤50 mg/kg; NH4+: ≤400 mg/kg; Ni: ≤5 mg/kg; Ni: ≤50 mg/kg; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: chloride (Cl-): ≤0.005%; chloride (Cl-): ≤5 mg/kg; chloride (Cl-): ≤50 mg/kg
• Linear Formula: NH2NH2 · H2SO4

DETAILS

MP Biomedicals - 02150130

Crystalline
Reagent for determination of C-terminal amino acids.

Sigma Aldrich - 455865

Packaging
25 g in poly bottle

Sigma Aldrich - 216046

Packaging
100, 500 g in poly bottle
5 g in glass bottle

REFERENCES

• Reagent for determination of C-terminal amino acid in peptides: Biochem. J ., 68, 475 (1958).