palladium

• ChemBase ID: 102673
• Molecular Formular: Pd
• Molecular Mass: 106.42
• Monoisotopic Mass: 105.903486
• SMILES: [Pd]
• Canonical SMILES: [Pd]
• InChI: InChI=1S/Pd
• InChIKey: KDLHZDBZIXYQEI-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: palladium
• IUPAC Traditional name: palladium
• Synonyms: PALLADIUM, 10% ON SrCO3; PALLADIUM, WIRE, 0.05 INCH DIAMETER; Pd/C; Palladium on carbon; Precipitated palladium; Palladium black; Palladium on activated alumina; Escat™ 11; PALLADIUM BLACK; Lindlar catalyst; Palladium powder, spherical, APS 0.5-1.7 micron; Palladium rod, 4.0mm (0.16in) dia; Palladium, plasma standard solution, Specpure®, Pd 1000 g/ml; Palladium wire, 2.0mm (0.08in) dia; Palladium, plasma standard solution, Specpure®, Pd 10,000 g/ml; Palladium wire, 0.01mm (0.0004in) dia; Palladium, AAS standard solution, Specpure®, Pd 1000 g/ml; Palladium powder, APS 0.25-0.55 micron; Palladium powder, -22 mesh, Premion®; Palladium wire, 0.25mm (0.01in) dia, Premion®; Escat™ 103; Palladium on activated charcoal; Palladium on alumina; Pd/BaSO4; Rosenmund catalyst; Palladium on barium sulfate; Palladium; PALLADIUM, SPONGE; PALLADIUM, 5% ON CHARCOAL; PALLADIUM, 10% ON CALCIUM CARBONATE; Palladium wire, 0.25mm (0.01in) dia; Palladium wire, 1.0mm (0.04in) dia; Palladium wire, 0.127mm (0.005in) dia; Palladium wire, 0.5mm (0.02in) dia; Palladium rod, 6.35mm (0.25in) dia; Palladium granules; Palladium powder, -200 mesh; Palladium foil, 2.0mm (0.08in) thick; Palladium foil, 1.0mm (0.04in) thick; Palladium foil, 0.5mm (0.02in) thick; Palladium foil, 0.1mm (0.004in) thick; Palladium foil, 0.025mm (0.001in) thick; Palladium foil, 0.25mm (0.01in) thick; Palladium foil, 1.0mm (0.04in) thick, Premion®; Palladium wire, 0.1mm (0.004in) dia, Premion®; Palladium wire, 0.5mm (0.02in) dia, Premion®; Palladium sponge, -100+325 mesh; Palladium powder, -60 mesh; Palladium slug, 6.35mm (0.25in) dia x 6.35mm (0.25in) length; Palladium Thinfoil, 0.005mm (0.0002in) thick; Palladium Thinfoil, 0.0125mm (0.0005in) thick; Palladium wire, 0.05mm (0.002in) dia, hard; 碳负载钯; 沉淀钯; 钯黑; 活性氧化铝负载钯; 钯粒; 钯线, 0.25mm (0.01in) 直径; 钯粉, 球状, APS 0.5-1.7微米; 钯棒, 4.0mm (0.2in) 直径; 钯,等离子标准溶液, Specpure®, Pd 1000®g/ml; 钯线, 2.0mm (0.08in) 直径; 钯,等离子标准溶液, Specpure®, Pd 10,000®g/ml; 钯线, 0.01mm (0.0004in) 直径; 钯, AAS标准溶液, Specpure®, Pd 1000 μg/ml; 钯粉, APS 0.25-0.55 微米; 钯粉, -22 目, Premion®; 钯丝, 0.25mm (0.01in) 直径, Premion®; 活性炭负载钯; 氧化铝负载钯; 硫酸钡负载钯; 钯; 钯丝, 0.25mm (0.01in) 直径; 钯丝, 1.0mm (0.04in) 直径; 钯丝, 0.127mm (0.005in) 直径; 钯丝, 0.5mm (0.02in) 直径; 钯棒, 6.35mm (0.25in) 直径; 钯颗粒; 钯粉, -200目; 钯箔, 2.0mm (0.08in)厚; 钯箔, 1.0mm (0.04in) 厚; 钯箔, 0.5mm (0.02in) 厚; 钯箔, 0.1mm (0.004in) 厚; 钯箔, 0.025mm (0.001in) 厚; 钯箔, 0.25mm (0.01in) 厚; 钯箔, 1.0mm (0.04in) 厚, Premion®; 钯丝, 0.1mm (0.004in) 直径, Premion®; 钯丝, 0.5mm (0.02in) 直径, Premion®; 海绵状钯, -100+325目; 细薄钯箔, 0.005mm (0.0002in)厚; 钯粉, -60目; 钯柱, 6.35mm (0.25in) 直径 x 6.35mm (0.25in) 长; 钯薄箔, 0.005mm (0.0002in) 厚; 钯薄箔, 0.0125mm (0.0005in) 厚; 钯线, 0.05mm (0.002in) 直径, 硬质

Database IDs

• CAS Number: 7440-05-3
• EC Number: 215-691-6; 231-595-7; 232-595-7; 231-115-6
• MDL Number: MFCD03457879; MFCD03427452; MFCD03613603; MFCD01074898; MFCD00011167; MFCD03613602; MFCD03613605; MFCD00192595; MFCD03427451
• PubChem SID: 24861597; 162088166; 24865747; 24859832; 24856713; 24852353; 24874174; 24874177; 24886912; 24886914; 24861454; 24852345; 24861456; 24856499; 24874173; 24861605; 24852078; 24859610; 24859611; 24856200; 24886919; 24867564; 24883257; 24856199; 24870204; 24886911; 24874156; 24859833; 24852342; 24886913; 24861601; 24857275; 24856201; 24854249; 24859609; 24865442; 24852084; 24852340; 24863195; 24874157; 24863196; 24853652; 24852218; 24859834; 24861603; 24883258; 24852341; 24886917; 24852217; 24874172; 24852344; 24856198; 24886920; 24852339; 24874171
• PubChem CID: 23938

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.0
• LogD (pH = 7.4): 0.0
• Log P: 0.0
• Molar Refractivity: 0.0 cm^3
• Polarizability: 4.9972634 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: (wet); ≈0.0236g/m Temper: as drawn; ≈0.037g/25x25mm, Light tight, no visible pinholes; ≈0.037g/25x25mm, not certified pinhole free; ≈0.094g/25x25mm, not certified pinhole free; ≈0.094mg/m, Temper: as drawn; ≈0.09g/m; ≈0.15g/m; ≈0.2g/25x25mm; ≈0.6g/m; ≈0.75g/25x25mm; ≈1.5g/cm; ≈1.9g/25x25mm; ≈15g/25x25mm; ≈2.36g/m; ≈2.41g/slug; ≈3.80g/cm; ≈3.8g/25x25mm; ≈37.7g/m; ≈7.5g/25x25mm; ≈9.44g/m; 300m2/g; 4x8 Mesh, 900-1100m2/g; 900-1100m2/g; Dark grey powder; dry; evaporation slug; foil; granular; Liquid; nanopowder; pellets; powder; Powder; powder, reduced, dry; rod; S.A. typically 20m2/g; shot; spheres; Spherical powder; sponge; tablets; Tap density 2.4-5.0g/cm3, S.A. 0.7-2.0m2/g; wire
• Melting Point: 1552 °C(lit.); 1554 °C(lit.); 1555?C
• Boiling Point: 2970 °C(lit.)
• Density: 12.02 g/cm3(lit.)
• Resistivity: 9.96 μΩ-cm, 20°C

Safety Information

• Storage Condition: Room Temperature (15-30°C)
• RTECS: RT3480500
• European Hazard Symbols: Corrosive (C); Flammable (F); Nature polluting (N); Toxic (T); X; Irritant (Xi)
• UN Number: 3089; UN1564; UN1789; UN3077; UN3089; UN3178
• German water hazard class: -; 3; nwg
• Hazard Class: 4.1; 6.1; 8; 9
• Packing Group: 2; II; III
• Australian Hazchem: 4Z
• Risk Statements: 11; 11-36/37/38; 22; 34; 34-37; 36/37/38; 61-33-62-51/53; R:10
• Safety Statements: 23-26-36/37/39-45; 23-26-36/37/39-45-60; 24/25; 26; 26-37-60; 33; 53-36/37-45-57-60; S:9-16-29
• EU Classification: F3
• EU Hazard Identification Number: 4.1B
• Emergency Response Guidebook(ERG) Number: 170
• TSCA Listed: 是
• GHS Pictograms: GHS02; GHS05; GHS06; GHS07; GHS08; GHS09
• GHS Signal Word: Danger; Warning
• GHS Hazard statements: H228; H228-H315-H319-H335; H301; H302 + H332; H314-H335; H315-H319; H315-H319-H335; H360-H303-H333-H411
• GHS Precautionary statements: P210-P241-P280-P240-P370+P378A; P210-P261-P305 + P351 + P338; P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A; P261-P305 + P351 + P338; P264-P270-P301+P310-P321-P405-P501A; P281-P273-P304+P312-P312-P405-P501A; P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves; Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• RID/ADR: UN 3089 4.1/PG 2

Product Information

• Purity: ~99.99%; ≥99.5% trace metals basis; ≥99.9%; ≥99.9% trace metals basis; 0.12%, Ruthenium, 0.12%; on 3mm alumina tablets; 0.47-0.53 wt. % palladium (Pd) basis; 0.5% on 2-4 mm alumina spheres; 0.5% on 3.18mm (0.125in) alumina pellets, reduced; 0.5% on 3.18mm (0.125in) alumina pellets, unreduced; 0.5% on granular carbon, reduced; 1% on activated carbon powder, eggshell, reduced, nominally 50% water wet; 1% on activated carbon powder, standard, reduced, nominally 50% water wet; 1% on activated carbon powder, standard, unreduced, nominally 50% water wet; 1% on alumina powder, reduced; 10% on activated carbon powder, eggshell, unreduced, nominally 50% water wet; 10% on activated carbon powder, standard, reduced, nominally 50% water wet; 10% on activated carbon powder, standard, unreduced, nominally 50% water wet; 10% on activated carbon powder, Type 58, standard, reduced, nominally 50% water wet; 10% Pd basis; 10% Pd basis (based on dry substance); 20% on activated carbon powder, eggshell, reduced, nominally 50% water wet; 20% on activated carbon powder, eggshell, unreduced, nominally 50% water wet; 20% on activated carbon powder, standard, reduced, nominally 50% water wet; 20% on activated carbon powder, standard, unreduced, nominally 50% water wet; 3% on activated carbon powder, eggshell, reduced; 3% on activated carbon powder, eggshell, unreduced, nominally 50% water wet; 3% on activated carbon powder, standard, reduced, nominally 50% water wet; 3% on activated carbon powder, standard, unreduced, nominally 50% water wet; 5% on 3mm alumina pellets; 5% on activated carbon powder, standard, reduced, acidic catalyst, nominally 50% water wet; 5% on activated carbon powder, standard, unreduced, nominally 50% water wet; 5% on activated carbon powder, Type A102023-5, standard, reduced, nominally 50% water wet; 5% on activated carbon powder, Type A401102-5, eggshell unreduced, nominally 50% water wet; 5% on activated carbon powder, Type A503023-5, eggshell, reduced, nominally 50% water wet; 5% on barium carbonate powder, reduced; 5% on barium sulfate powder, reduced; 5% on barium sulfate powder, unreduced; 5% on calcium carbonate powder, reduced; 5% on calcium carbonate, Type A306060-5, lead poisoned; 5% on charcoal paste, Type 39, 50-65% water wet; 5% on gamma alumina powder, reduced; 5% on strontium carbonate powder, reduced; 5% Pd basis; 5% Pd basis (based on dry substance); 8%, Platinum, 2%; on activated carbon powder, nominally 50% water wet; 99.8% (metals basis); 99.9% (metals basis); 99.9% trace metals basis; 99.95%; 99.95% (metals basis); 99.95% trace metals basis; 99.95+% (metals basis); 99.97% (metals basis); 99.98%; 99.98% trace metals basis; 99.98+% (metals basis); 99.99%; 99.99% (metals basis); 99.99% trace metals basis; 99.99+% (metals basis); 99.995% (metals basis); 99.999% trace metals basis
• Grade: coating quality; puriss.
• Particle Size: <1 μm; <25 nm (TEM); <75 μm; 0.25-2.36 mm; 1.0-1.5 μm; 3.2 mm; 4-8 mesh
• Description: Degussa type E214R/D
• Contains: ~50% water; ~50% water as stabilizer; ≤50% water
• Surface Area: 40-60 m2/g
• Extent of Labeling: 0.5 wt. % loading; 1 wt. % loading; 10 wt. % loading; 10 wt. % loading (dry basis); 3 wt. % loading; 30 wt. % loading; 5 wt. % loading; 5 wt. % loading (dry basis)
• Matrix: activated carbon support; activated carbon, wet support; carbon powder, wet support; carbon, dry support; carbon, wet support
• Quality: moistened with water
• Diameter: 0.1 mm; 0.25 mm; 0.5 mm; 1 mm; 1.0 mm; 1-8 mm; 3.1 mm; 6.25 mm
• Thickness: 0.025 mm; 0.05 mm; 0.1 mm; 0.127 mm; 0.25 mm; 0.5 mm; 1.0 mm
• Weight: 10.9 g (one slug); 2.4 g (one slug); Unit weight excludes weight of water; Unit wt. excludes wt. of H2O
• diam. × L: 0.6 cm × 0.6 cm; 0.9 cm × 1.2 cm
• Wire diameter: 0.127 mm; 0.5 mm
• Linear Formula: Pd
• Empirical Formula (Hill Notation): Pd

DETAILS

MP Biomedicals - 05224379

MP Biomedicals Rare Chemical collection

MP Biomedicals - 05217274

MP Biomedicals Rare Chemical collection

MP Biomedicals - 05205558

MP Biomedicals Rare Chemical collection

MP Biomedicals - 02102549

Catalyst
Powder
Purity: ~99.99%

MP Biomedicals - 05205557

MP Biomedicals Rare Chemical collection

MP Biomedicals - 05224380

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 205702

Packaging
25 g in glass bottle

Sigma Aldrich - 330116

Application
A high activity grade, used especially for Z-group cleavage.
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 75990

Other Notes
Catalyst for dehydrogenations1
Packaging
1, 10, 50 g in glass bottle

Sigma Aldrich - 520829

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 348694

Packaging
960 mg in rigid mailer
Quantity
960 mg = 40 cm; 4.8 g = 200 cm

Sigma Aldrich - 76020

Application
Hydrogenation catalyst
Usually supported on BaSO4, or an appropriate form of carbon, and useful catalyst for hydrogenations
Packaging
10 g in poly bottle

Sigma Aldrich - 267112

Packaging
9 g in rigid mailer
900 mg in rigid mailer
Quantity
900 mg = 10 cm; 9 g = 100 cm

Sigma Aldrich - 203998

Packaging
1 g in glass bottle
5 g in poly bottle

Sigma Aldrich - 205745

Packaging
50, 250 g in glass bottle

Sigma Aldrich - 520810

Packaging
1, 5 g in glass bottle

Sigma Aldrich - 267082

Packaging
1, 5 g in glass bottle

Sigma Aldrich - 411450

Packaging
1.5 g in rigid mailer
375 mg in rigid mailer
Quantity
375 mg = 25 × 25 mm; 1.5 g = 50 × 50 mm

Sigma Aldrich - 440086

Packaging
1, 5, 25 g in glass bottle

Sigma Aldrich - 346993

Packaging
1.9 g in glass bottle
Quantity
1.9 g = 2 cm; 9.5 g = 10 cm

Sigma Aldrich - 464651

Packaging
25 g in poly bottle
5 g in glass bottle

Sigma Aldrich - 203939

Packaging
1 g in glass bottle
5 g in poly bottle

Sigma Aldrich - 346985

Packaging
7.6 g in glass bottle
Quantity
7.6 g = 2 cm; 38 g = 10 cm

Sigma Aldrich - 276707

Packaging
10, 50 g in glass bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6

Sigma Aldrich - 520888

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenatearomatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 407305

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
1, 10 g in glass bottle

Sigma Aldrich - 326666

General description
Average particle size determined by Fisher sub-sieve sizer
Packaging
1, 5 g in glass bottle

Sigma Aldrich - 348643

包装
1.9 g in rigid mailer
Quantity
1.9g = 25×25mm；7.6g = 50×50mm

Sigma Aldrich - 227757

Packaging
10, 50 g in glass bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6

Sigma Aldrich - 76022

Application
Usually supported on BaSO4, or an appropriate form of carbon, and useful catalyst for hydrogenations.
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 348678

Packaging
7.6 g in rigid mailer
Quantity
7.6 g = 25 × 25 mm; 30.4 g = 50 × 50 mm

Sigma Aldrich - 75993

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 205672

Application
catalyst for hydrogenation and hydrogenolysis
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
25, 100 g in glass bottle

Sigma Aldrich - 520675

Packaging
25 g in poly bottle

Sigma Aldrich - 267139

Quantity
750 mg = 25 × 25 mm

Sigma Aldrich - 277991

Application
Catalyst for the hydrogenation, the Rosenmund reduction.
Packaging
1, 10, 50 g in glass bottle

Sigma Aldrich - 75992

Packaging
1, 10, 50 g in poly bottle

Sigma Aldrich - 237515

Packaging
10, 50 g in glass bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6

Sigma Aldrich - 326690

Quantity
600 mg = 1 m; 3 g = 5 m

Sigma Aldrich - 520667

Packaging
25 g in poly bottle

Sigma Aldrich - 287474

Packaging
3.8 g in rigid mailer
Quantity
3.8 g = 25 × 25 mm; 15.2 g = 50 × 50 mm

Sigma Aldrich - 330108

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Useful reagent for debenzylations and decarboxybenzylations.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
1, 10, 50 g in glass bottle

Sigma Aldrich - 520837

Packaging
10 g in glass bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Legal Information
ESCAT is a trademark of BASF Catalysts, LLC

Sigma Aldrich - 205834

Packaging
1, 5 g in glass bottle
250 mg in glass bottle

Sigma Aldrich - 205699

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
1, 10, 50 g in glass bottle

Sigma Aldrich - 330124

Application
Reagent especially useful in the reduction of fatty acids and bulky molecules.
catalyst for hydrogenation and hydrogenolysis
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 520845

Packaging
10 g in poly bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Legal Information
ESCAT is a trademark of BASF Catalysts, LLC

Sigma Aldrich - 643173

Application
Useful for the catalytic hydrogenation of functional groups.
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 373192

Packaging
10.9 g in glass bottle

Sigma Aldrich - 686468

Packaging
500 mg in glass bottle

Sigma Aldrich - 205680

Application
Catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; used for hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; used to dehydrogenate aromatics and deformylate aldehydes.
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6
Packaging
10, 50, 100 g in glass bottle

Sigma Aldrich - 205753

Packaging
25, 100 g in glass bottle
Application
Catalyst for:
• Stille reaction1
• Hydrogenation reactions2
• Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions3
• Deoxygenation4
• Oxidation reactions5
• Coupling reactions6

Sigma Aldrich - 643181

Application
Heterogeneous catalyst for carbon-carbon coupling reactions (Heck and Suzuki)
catalyst for hydrogenation of alkenes, alkynes, ketones, nitriles,imines, azides, nitro groups, benzenoid and heterocyclic aromatics;used for hydrogenolysis of cyclopropanes, benzyl derivatives,epoxides, hydrazines, and halides; used to dehydrogenatearomatics and deformylate aldehydes. (Delete old application
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 205710

Packaging
10, 100 g in glass bottle

Sigma Aldrich - 373206

Packaging
2.4 g in glass bottle

Sigma Aldrich - 267120

Packaging
190 mg in rigid mailer
Quantity
190 mg = 25 × 25 mm; 760 mg = 50 × 50 mm

Sigma Aldrich - 348708

Quantity
180 mg = 2 m

Sigma Aldrich - 205729

Application
Catalyst used to catalyze the hydrogenation of acyl chlorides to aldehydes,the Rosenmund reduction; useful catalyst for many otherhydrogenations
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 326658

Packaging
1 g in glass bottle

Sigma Aldrich - 75991

Packaging
10, 50 g in glass bottle

REFERENCES

• Deactivated hydrogenation catalyst, useful for selective reductions.
• Effective for the deprotection of O-benzyl hydroxamates to give peptide hydroxamic acids: Tetrahedron Lett., 36, 197 (1995).
• For use in conjunction with quinoline and sulfur for the Rosenmund reduction of acid chlorides to aldehydes, see: Org. Synth. Coll., 3, 551 (1955). Review: Org. React., 4, 362 (1948).
• For use in presence of quinoline for the partial hydrogenation of an acetylene to a cis-olefin, see: Org. Synth. Coll., 8, 609 (1993); see also Palladium, 43172.