O-[(sulfoperoxy)sulfonyl]oxidanol diamine

• ChemBase ID: 102109
• Molecular Formular: H8N2O8S2
• Molecular Mass: 228.20212
• Monoisotopic Mass: 227.97220723
• SMILES: N.N.OS(=O)(=O)OOS(=O)(=O)O
• Canonical SMILES: OS(=O)(=O)OOS(=O)(=O)O.N.N
• InChI: InChI=1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)
• InChIKey: ROOXNKNUYICQNP-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: O-[(sulfoperoxy)sulfonyl]oxidanol diamine
• IUPAC Traditional name: peroxydisulfuric acid diamine
• Synonyms: AP; APS; PER; Ammonium peroxodisulfate; Ammonium peroxydisulfate; Ammonium persulfate; 6-Aminopurine; Vitamin B4; ADENINE FREE BASE; 过二硫酸铵; 过氧二硫酸铵; 过硫酸铵

Database IDs

• CAS Number: 7727-54-0; 73-24-5
• EC Number: 200-796-1; 231-786-5
• MDL Number: MFCD00003390
• PubChem SID: 24890800; 24854939; 24852905; 24890771; 24891401; 24858843; 24891238; 162088734
• PubChem CID: 16211170

CALCULATED PROPERTIES

• Acid pKa: -3.4752414
• H Acceptors: 6
• H Donor: 2
• LogD (pH = 5.5): -5.686493
• LogD (pH = 7.4): -5.6864934
• Log P: -0.9336958
• Molar Refractivity: 25.1128 cm^3
• Polarizability: 12.317812 Å^3
• Polar Surface Area: 127.2 Å^2
• Rotatable Bonds: 3
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: H2O: soluble; H2O: soluble0.5 M at 20 °C, clear, colorless; H2O: soluble1 M at 20 °C, clear, colorless
• Apperance: capsule; powder
• Melting Point: >360°C
• Vapor Density: 7.9 (vs air)
• pH: 1.0-2.0 (25 °C, 1 M in H2O)

Safety Information

• Storage Condition: Room Temperature (15-30°C)
• RTECS: AU6125000; SE0350000
• European Hazard Symbols: Oxidising (O); Harmful (Xn)
• UN Number: 1444
• German water hazard class: 1
• Hazard Class: 5.1
• Packing Group: 3
• Risk Statements: 8-22-36/37/38-42/43; R:22
• Safety Statements: 22-24-26-37; S:36/37/39
• GHS Pictograms: GHS03; GHS07; GHS08
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H302-H315-H317-H319-H334-H335
• GHS Precautionary statements: P220-P261-P280-P305 + P351 + P338-P342 + P311
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1444 5.1/PG 3

Product Information

• Purity: ≥95.0%; ≥97.0%; ≥98%; ≥98.0%; ≥98.0% (RT); ≥99.0%; ≥99.99%; 98%; 99%
• Grade: ACS reagent; for electrophoresis; for molecular biology; JIS special grade; puriss.; puriss. p.a.; purum p.a.; reagent grade; ReagentPlus®; SAJ first grade
• Ignition Residue: ≤0.05%; ≤0.05% (as SO4); ≤0.1% (as SO4)
• Impurities: <100 ppm total metallic impurities; ≤0.0005% Phosphorus (P); ≤0.001% heavy metals (as Pb); ≤0.003% heavy metals (as Pb); ≤0.005% Insoluble matter; ≤0.005% insolubles; ≤0.04 meq/g Titr. Acid; ≤0.04 meq/g Titr. acid; ≤0.2% free acid; ≤0.2% free acid (as H2SO4); insoluble matter, passes filter test
• Cation Traces: Al: ≤0.0005%; Al: ≤5 mg/kg; As: ≤0.1 mg/kg; Ba: ≤5 mg/kg; Bi: ≤5 mg/kg; Ca: ≤0.001%; Ca: ≤10 mg/kg; Ca: ≤50 mg/kg; Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤5 mg/kg; Cu: ≤0.0005%; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: <10 ppm; Fe: ≤0.0005%; Fe: ≤0.001%; Fe: ≤10 mg/kg; Fe: ≤10 ppm; heavy metals (as Pb): <50 ppm; heavy metals (as Pb): ≤0.005%; heavy metals (as Pb): ≤50 ppm; heavy metals: ≤0.005%; K: ≤0.005%; K: ≤100 mg/kg; K: ≤50 mg/kg; Li: ≤5 mg/kg; Mg: ≤0.0005%; Mg: ≤5 mg/kg; Mn: ≤0.0001%; Mn: ≤0.5 mg/kg; Mn: ≤0.5 ppm; Mn: ≤2 mg/kg; Mn: ≤5 mg/kg; Mo: ≤5 mg/kg; Na: ≤0.01%; Na: ≤500 mg/kg; Ni: ≤5 mg/kg; Ni: ≤50 mg/kg; Pb: ≤0.001%; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Sr: ≤5 mg/kg; Zn: ≤0.0005%; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: chloride (Cl-): <10 ppm; chloride (Cl-): ≤0.001%; chloride (Cl-): ≤10 ppm; chloride (Cl-): ≤20 mg/kg; chloride (Cl-): ≤5 mg/kg; chloride, chlorate (as Cl-): ≤10 mg/kg; Cl- and ClO4-: ≤0.001%
• Product Line: BioReagent; BioUltra; BioXtra
• abs.: absorption1M/308 nm, H2O cut-off
• Linear Formula: (NH4)2S2O8

DETAILS

MP Biomedicals - 02100190

Free Base
Crystalline
Purity: 99%
Used as a blood preservative and in viral research.

Sigma Aldrich - A3678

Analysis Note
Tested for use in acrylamide polymerization.
Application
Ammonium persulfate forms oxygen free radicals in aqueous solution by a base-catalyzed mechanism1. The bases most commonly used as catalysts are tertiary amines such as N,N,N′,N′-tetramethylethylenediamine (TEMED) or 3-dimethylaminopropionitrile (DMAPN). The free radicals will cause acrylamide and bis-acrylamide to polymerize to form a gel matrix, which can be used for separating macromolecules by size.
Catalyst for acrylamide gel polymerization.
Packaging
25, 100 g in poly bottle

Sigma Aldrich - A3426

Application
Catalyst for acrylamide gel polymerization.
Quantity
150 mg per capsule
Reconstitution
Suggested use is 250 μL of a 10% APS stock solution for 50 mL acrylamide gel solution. Stock solution may be stored at 4 °C for several weeks.

Sigma Aldrich - A9164

Application
Catalyst for acrylamide gel polymerization.
Packaging
25, 100 g in poly bottle
Reconstitution
10% stock solution may be stored at 4 °C for several weeks.

Sigma Aldrich - 431532

Application
Catalyst for acrylamide gel polymerization.
Features and Benefits
Meets A.C.S. reagent specifications.
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Sigma Aldrich - 09914

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 09915

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 09920

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 31117

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 248614

Application
Catalyst for acrylamide gel polymerization.
Packaging
100, 500 g in poly bottle
2.5, 4×2.5 kg in poly bottle
5 g in glass bottle

Sigma Aldrich - 11222

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 215589

Application
Catalyst for acrylamide gel polymerization.
Free radical initiator
Packaging
100, 500 g in poly bottle
2.5 kg in poly bottle

Sigma Aldrich - A7460

Application
Catalyst for acrylamide gel polymerization.
Packaging
100, 500 g in poly bottle

Sigma Aldrich - 01-4930

Application
Catalyst for acrylamide gel polymerization.
Suitability
for electrophoresis

Sigma Aldrich - 01-4910

Application
Catalyst for acrylamide gel polymerization.

Sigma Aldrich - 01-4920

Application
Catalyst for acrylamide gel polymerization.