diphenyliodanium; hexafluoro-$l^{5}-phosphanuide

• ChemBase ID: 100066
• Molecular Formular: C12H10F6IP
• Molecular Mass: 426.0764502
• Monoisotopic Mass: 425.94690427
• SMILES: [I+](c1ccccc1)c1ccccc1.[P-](F)(F)(F)(F)(F)F
• Canonical SMILES: c1ccc(cc1)[I+]c1ccccc1.F[P-](F)(F)(F)(F)F
• InChI: InChI=1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1
• InChIKey: DSSRLRJACJENEU-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: diphenyliodanium; hexafluoro-$l^{5}-phosphanuide; diphenyliodanium; hexafluoro-λ^5-phosphanuide
• IUPAC Traditional name: diphenyliodanium; hexafluoro-$l^{5}-phosphanuide; diphenyliodanium hexafluorophosphate
• Synonyms: Diphenyliodonium hexafluorophosphate 97%; DPIHFP; Diphenyliodonium hexafluorophosphate; 二苯基碘鎓六氟磷酸盐; 六氟磷酸二苯基碘鎓盐

Database IDs

• CAS Number: 58109-40-3
• EC Number: 261-134-5
• MDL Number: MFCD00061398
• Beilstein Number: 4343861
• PubChem SID: 162086493; 24866948; 24879004
• PubChem CID: 2737136

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 4.5634055
• LogD (pH = 7.4): 4.5634055
• Log P: 4.5634055
• Molar Refractivity: 64.8948 cm^3
• Polarizability: 28.086405 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 2
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Melting Point: 139-144°C; 140-144 °C; 140-144 °C(lit.); 142°C

Safety Information

• Storage Warning: Irritant; Light Sensitive
• European Hazard Symbols: Corrosive (C); X
• UN Number: 1759; UN2811
• German water hazard class: 3
• Hazard Class: 6.1; 8
• Packing Group: 3; III
• Risk Statements: 20/21/22-36/37/38; 34
• Safety Statements: 26-36/37/39-45; 9-26-36/37-60
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H314; H331-H302-H312-H315-H319-H335
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A; P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1759 8/PG 3

Product Information

• Purity: ≥98%; ≥98.0% (TLC); 98%
• Grade: purum
• Linear Formula: (C6H5)2I(PF6)

DETAILS

Sigma Aldrich - 548014

Application
Cationic photoinitiator. Photoacid generator.
Packaging
5, 25 g in amber poly

Sigma Aldrich - 43087

Other Notes
Catalyst for the photochemical polymerization of various monomers1,2